{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,4]],"date-time":"2026-11-04T15:04:02Z","timestamp":1793804642048,"version":"4.6.1"},"reference-count":20,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2023,1,17]],"date-time":"2023-01-17T00:00:00Z","timestamp":1673913600000},"content-version":"am","delay-in-days":341,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2022,2,10]],"date-time":"2022-02-10T00:00:00Z","timestamp":1644451200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE\u20100963450"],"award-info":[{"award-number":["CHE\u20100963450"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE\u20101950585"],"award-info":[{"award-number":["CHE\u20101950585"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2022,4,30]]},"abstract":"<jats:sec>\n                    <jats:title>Rationale<\/jats:title>\n                    <jats:p>\n                      Building on our report that collision\u2010induced dissociation (CID) can be used to create the highly reactive U\u2010alkylidyne species [O=U\u2261CH]\n                      <jats:sup>+<\/jats:sup>\n                      , our goal was to determine whether the species could be as an intermediate for synthesis of [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      by reaction with carbon disulfide (CS\n                      <jats:sub>2<\/jats:sub>\n                      ).\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Methods<\/jats:title>\n                    <jats:p>\n                      Cationic uranyl\u2010propiolate precursor ions were generated by electrospray ionization, and multiple\u2010stage CID in a linear trap instrument was used to prepare [O=U\u2261CH]\n                      <jats:sup>+<\/jats:sup>\n                      . Neutral CS\n                      <jats:sub>2<\/jats:sub>\n                      was admitted into the trap through a modified He inlet and precision leak valves.\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Results<\/jats:title>\n                    <jats:p>\n                      The [O=U\u2261CH]\n                      <jats:sup>+<\/jats:sup>\n                      ion reacts with CS\n                      <jats:sub>2<\/jats:sub>\n                      to generate [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      . CID of [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      causes elimination of the axial sulfide ligand to generate [OU]\n                      <jats:sup>+<\/jats:sup>\n                      . Using isotopically labeled reagent, we found that [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      reacts with O\n                      <jats:sub>2<\/jats:sub>\n                      to create [UO\n                      <jats:sub>2<\/jats:sub>\n                      ]\n                      <jats:sup>+<\/jats:sup>\n                      .\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Conclusions<\/jats:title>\n                    <jats:p>\n                      [O=U\u2261CH]\n                      <jats:sup>+<\/jats:sup>\n                      proves to be a useful reagent ion for synthesis of [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      , a species that to date has only been created by gas\u2010phase reactions of U\n                      <jats:sup>+<\/jats:sup>\n                      and U\n                      <jats:sup>2+<\/jats:sup>\n                      . Dissociation of [OUS]\n                      <jats:sup>+<\/jats:sup>\n                      to create [OU]\n                      <jats:sup>+<\/jats:sup>\n                      , but not [US]\n                      <jats:sup>+<\/jats:sup>\n                      , and the efficient conversion of the species into [UO\n                      <jats:sub>2<\/jats:sub>\n                      ]\n                      <jats:sup>+<\/jats:sup>\n                      , is consistent with the relative differences in U\u2013O and U\u2013S bond energies.\n                    <\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/rcm.9260","type":"journal-article","created":{"date-parts":[[2022,1,18]],"date-time":"2022-01-18T02:34:44Z","timestamp":1642473284000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Intrinsic reactivity of [OUCH]\n                    <sup>+<\/sup>\n                    : Apparent synthesis of [OUS]\n                    <sup>+<\/sup>\n                    by reaction with CS\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"36","author":[{"given":"Luke J.","family":"Metzler","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christopher T.","family":"Farmen","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Allison N.","family":"Fry","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mark P.","family":"Seibert","sequence":"additional","affiliation":[{"name":"Chemistry Department Gettysburg College  Gettysburg PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kayla A.","family":"Massari","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5716-1188","authenticated-orcid":false,"given":"Theodore A.","family":"Corcovilos","sequence":"additional","affiliation":[{"name":"Department of Physics Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7100-4370","authenticated-orcid":false,"given":"Michael J.","family":"van Stipdonk","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Duquesne University  Pittsburgh PA USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,2,10]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp4113798"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02420"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp5066067"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP00494F"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b01720"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b01265"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13361-019-02179-6"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2017.11.016"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP01520F"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2021.116664"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP00177A"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT04484A"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT00530G"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc39053e"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(80)87022-4"},{"key":"e_1_2_7_17_1","first-page":"4162","article-title":"Synthesis and properties of uranium sulfide cations. 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