{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,11]],"date-time":"2025-11-11T15:29:04Z","timestamp":1762874944584},"reference-count":40,"publisher":"Wiley","issue":"8-9","license":[{"start":{"date-parts":[[2005,6,13]],"date-time":"2005-06-13T00:00:00Z","timestamp":1118620800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Small"],"published-print":{"date-parts":[[2005,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p><jats:italic>Solid\u2013solid interfacial processes greatly affect the performance of electronic and composite materials, but probing the dynamics of buried interfaces is challenging and often involves lengthy or invasive sample preparation. We show that bilayer nanoribbons\u2014made here of tin dioxide and copper\u2014are convenient structures for observing as\u2010made interfaces as they respond to changing temperature in a transmission electron microscope (TEM). At low temperatures (&lt;200\u2009\u00b0C), differential thermal expansion causes the bilayers to bend when heated or cooled, with the motion determined by the extent of Cu\u2013SnO<jats:sub>2<\/jats:sub> epitaxy. At higher temperatures, we are able to watch\u2014in real time and with nanometer resolution\u2014a progression of grain growth, interdiffusion, island formation, solid\u2010state chemical reactions, and melting. This novel TEM geometry is readily applicable to other nanoribbon\/coating combinations and is well suited to observing interfacial phenomena driven thermally or by the application of mechanical, electrical, or magnetic forces.<\/jats:italic><\/jats:p>","DOI":"10.1002\/smll.200500114","type":"journal-article","created":{"date-parts":[[2005,6,13]],"date-time":"2005-06-13T10:24:36Z","timestamp":1118658276000},"page":"858-865","source":"Crossref","is-referenced-by-count":24,"title":["Thermally Driven Interfacial Dynamics of Metal\/Oxide Bilayer Nanoribbons"],"prefix":"10.1002","volume":"1","author":[{"given":"Matt","family":"Law","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao Feng","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rong","family":"Yu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tevye","family":"Kuykendall","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peidong","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,7,20]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00339-003-2438-4"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0206667"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.60.1406"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1203"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1058120"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.56.R10079"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.359789"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1069325"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1327281"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja030235l"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl0257216"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1528301"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-6090(01)01351-7"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4615-9597-7"},{"key":"e_1_2_6_15_2","volume-title":"Roark\u2019s Formulas for Stress and Strain","author":"Roark R. J.","year":"1989"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1029\/JB080i017p02595"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.67.174110"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1557\/PROC-821-P2.3"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1086636"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1144509"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.276.5321.2021"},{"key":"e_1_2_6_22_2","doi-asserted-by":"crossref","first-page":"1560","DOI":"10.1073\/pnas.98.4.1560","volume":"98","author":"Wu G.","year":"2001","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp048482e"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-0041-0_12"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1073404"},{"key":"e_1_2_6_26_2","unstructured":"The thermodynamic condition for the perfect wetting of a metal on an oxide surface is\u03b3interface=\u03b3oxide\u2212\u03b3metal where the terms refer to the free energies of the metal\/oxide interface and the clean oxide and metal surfaces respectively. If\u03b3interface>\u03b3oxide\u2212\u03b3metalthen the metal does not wet the oxide surface. Calculations (Refs.\u2005[39] and [40]) show that the free energy of SnO2{101} and {010} is markedly lower than that of Cu{111} (1.2\u20131.35\u2005J\u2009m\u22122versus 1.8\u20131.95\u2005J\u2009m\u22122). In general Cu\u2013oxide bonding typically involves mostly weak polarization interactions (minimal charge transfer) meaning that\u03b3interfaceis large and 3D islands should exist at equilibrium."},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(96)00591-2"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(91)90591-F"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.468237"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.47.13782"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1007\/s004600050275"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-5729(96)00011-8"},{"key":"e_1_2_6_33_2","unstructured":"Model oxide surfaces typically have a low density of defects to act as nucleation sites so that for certain systems 2D metal islands stop growing laterally and start growing vertically before they coalesce into a continuous layer. This results in 3D islands that cover a substantial fraction of the substrate. In contrast the nanoribbons are rich enough in surface defects (e.g. step edges and adsorbates) to nucleate a high density of islands that coalesce before reaching their critical size (see Refs.\u2005[32] and [37])."},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(95)00912-4"},{"key":"e_1_2_6_35_2","unstructured":"SnO2is at least 250\u2005kJ\u2009mol\u22121more stable than either Cu2O or CuO at the temperatures and oxygen partial pressure relevant here (see Ref.\u2005[38])."},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1557\/PROC-323-165"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0352175"},{"key":"e_1_2_6_38_2","volume-title":"Physical Chemistry of Metals","author":"Darken L. S.","year":"1953"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1594837"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0039-6028(98)00363-X"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fsmll.200500114","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.200500114","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,30]],"date-time":"2023-08-30T16:00:37Z","timestamp":1693411237000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.200500114"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,7,20]]},"references-count":40,"journal-issue":{"issue":"8-9","published-print":{"date-parts":[[2005,8]]}},"alternative-id":["10.1002\/smll.200500114"],"URL":"https:\/\/doi.org\/10.1002\/smll.200500114","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,7,20]]}}}