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In a first step, crystalline tungsten oxide W<jats:sub>18<\/jats:sub>O<jats:sub>49<\/jats:sub> nanowires with a diameter of about 1.5\u2009nm form via ether elimination reaction. Subsequently, the large residue of the benzyl alcohol is transformed to dibenzyl ether, which then polymerizes to polybenzylene, incorporating the nanoparticles into the forming polymer. The catalytic effect of the tungsten oxide nanowires on the quantitative formation of polybenzylene is proven by reacting them in different concentrations and at varying temperatures either with benzyl alcohol or with dibenzyl ether. Complete polymerization of benzyl alcohol is achieved within just 30\u2009min by using a particle\u2010to\u2010monomer molar ratio of 1:115 at 160\u2009\u2009\u00b0C. Lower reaction temperatures (100\u2013130\u2009\u2009\u00b0C) or higher ratios (1:340 and 1:680) prolong the reaction time to several hours. Further studies show that the tungsten oxide nanoparticles are able to completely polymerize various other alcohols with an aryl methanol group.<\/jats:p>","DOI":"10.1002\/smll.200902289","type":"journal-article","created":{"date-parts":[[2010,3,30]],"date-time":"2010-03-30T13:08:20Z","timestamp":1269954500000},"page":"960-966","source":"Crossref","is-referenced-by-count":30,"title":["Co\u2010operative Formation of Monolithic Tungsten Oxide\u2013Polybenzylene Hybrids via Polymerization of Benzyl Alcohol and Study of the Catalytic Activity of the Tungsten Oxide Nanoparticles"],"prefix":"10.1002","volume":"6","author":[{"given":"Inga","family":"Olliges\u2010Stadler","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marta D.","family":"Rossell","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus","family":"Niederberger","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,4,15]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/JM9960600511"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm011060m"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200300389"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b509097k"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527610495"},{"key":"e_1_2_6_6_2","first-page":"1007","volume":"18","author":"Sanchez C.","year":"1994","journal-title":"New J. 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