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Raman microspectroscopy is used to probe the temperature dependence of the spin state of the iron(II) ions in the films (40\u201390 nm in thickness), and reveals an incomplete but cooperative spin transition comparable to that of the bulk material. Adsorption\/desorption of pyridine guest molecules is found to have a substantial influence on the spin\u2010crossover properties of the thin layers. This interplay between host\u2013guest and spin\u2010crossover properties in thin films and nanopatterns demonstrates the potential ability of using this kind of material as a microsensor.<\/jats:p>","DOI":"10.1002\/smll.201101089","type":"journal-article","created":{"date-parts":[[2011,10,14]],"date-time":"2011-10-14T11:34:49Z","timestamp":1318592089000},"page":"3385-3391","source":"Crossref","is-referenced-by-count":57,"title":["Guest Effect on Nanopatterned Spin\u2010Crossover Thin Films"],"prefix":"10.1002","volume":"7","author":[{"given":"Carlos","family":"Bartual\u2010Murgui","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amal","family":"Akou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lionel","family":"Salmon","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G\u00e1bor","family":"Moln\u00e1r","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christophe","family":"Thibault","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jose Antonio","family":"Real","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Azzedine","family":"Bousseksou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,10,14]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2004.03.034"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300610"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/B618320B"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0nj00275e"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b804680h"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1007\/b95408"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15042a"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.279.5347.44"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010259y"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199420241"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200806039"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200904379"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja902187d"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/b805038b"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002451"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CS00042F"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00097a058"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm950346m"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/la0104424"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.03.022"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901090"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja800563h"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900378"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2769"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601885"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm8019878"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.200700448"},{"key":"e_1_2_6_28_2","author":"Bartual\u2010Murgui C.","year":"2011","journal-title":"New J. 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