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Some of these metal phosphides and phosphates and their hybrids compare favorably with transition metal oxides\/hydroxides, which have been studied extensively as a class of electrode materials for supercapacitor applications, where they have limitations in terms of electrical and ion conductivity and device stability. To be specific, metal phosphides have both metalloid characteristics and good electric conductivity. For metal phosphates, the open\u2010framework structures with large channels and cavities endow them with good ion conductivity and charge storage capacity. In this review, we present the recent progress on metal phosphides and phosphates, by focusing on their advantages\/disadvantages and potential applications as a new class of electrode materials in supercapacitors. The synthesis methods to prepare these metal phosphides\/phosphates are looked into, together with the scientific insights involved, as they strongly affect the electrochemical energy storage performance. Particular attentions are paid to those hybrid\u2010type materials, where strong synergistic effects exist. In the summary, the future perspectives and challenges for the metal phosphides, phosphates and hybrid\u2010types are proposed and discussed.<\/jats:p>","DOI":"10.1002\/smll.201701530","type":"journal-article","created":{"date-parts":[[2017,8,21]],"date-time":"2017-08-21T10:32:43Z","timestamp":1503311563000},"source":"Crossref","is-referenced-by-count":470,"title":["Metal Phosphides and Phosphates\u2010based Electrodes for Electrochemical Supercapacitors"],"prefix":"10.1002","volume":"13","author":[{"given":"Xin","family":"Li","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering National University of Singapore  117574 Singapore"},{"name":"Centre for Advanced 2D Materials and Graphene Research Centre National University of Singapore  117546 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdelnaby M.","family":"Elshahawy","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering 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