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Here, Zr is used as the metal center and 1,3,6,8\u2010tetra (4\u2010carboxylphenyl) pyrene (TBAPy) and tetrakis(4\u2010carboxyphenyl)porphyrin (TCPP) as double linkers to synthesize a novel Zr(TBAPy)<jats:sub>5<\/jats:sub>(TCPP) material. Results indicate that Zr(TBAPy)<jats:sub>5<\/jats:sub>(TCPP) can be used as a fluorescence turn\u2010on probe for highly selective and sensitive detection of H<jats:sub>2<\/jats:sub>S gas and its derivatives S<jats:sup>2\u2212<\/jats:sup> in aqueous solutions with an extremely low concentration (\u22481 ppb) and fast response time (&lt;10 s). Moreover, by tailoring the particle size of samples, it is found that Zr(TBAPy)<jats:sub>5<\/jats:sub>(TCPP) can efficiently achieve the visualization identification of fingerprints due to the fluorescence turn\u2010on effect. All the results indicate that the Zr(TBAPy)<jats:sub>5<\/jats:sub>(TCPP) is a promising multifunctional fluorescence turn\u2010on probe.<\/jats:p>","DOI":"10.1002\/smll.201703822","type":"journal-article","created":{"date-parts":[[2018,4,3]],"date-time":"2018-04-03T07:28:15Z","timestamp":1522740495000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":117,"title":["A Novel Zr\u2010MOF as Fluorescence Turn\u2010On Probe for Real\u2010Time Detecting H<sub>2<\/sub>S Gas and Fingerprint Identification"],"prefix":"10.1002","volume":"14","author":[{"given":"Lin","family":"Guo","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing University of Chemical Technology  Beijing 100029 P. R. 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