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Random resistive access memory (RRAM) is suitable for artificial synapse due to its tunable bidirectional switching behavior. In this work, a biological spiking synapse is developed with solution processed Au@Ag core\u2013shell nanoparticle (NP)\u2010based RRAM. The device shows highly controllable bistable resistive switching behavior due to the favorable Ag ions migration and filament formation in the composite film, and the good charge trapping and transport property of Au@Ag NPs. Moreover, comprehensive synaptic functions of biosynapse including paired\u2010pulse depression, paired\u2010pulse facilitation, post\u2010tetanic potentiation, spike\u2010time\u2010dependent plasticity, and the transformation from short\u2010term plasticity to long\u2010term plasticity are emulated. This work demonstrates that the solution processed bimetal core\u2013shell nanoparticle\u2010based biological spiking synapse provides great potential for the further creation of a neuromorphic computing system.<\/jats:p>","DOI":"10.1002\/smll.201800288","type":"journal-article","created":{"date-parts":[[2018,5,28]],"date-time":"2018-05-28T06:46:11Z","timestamp":1527489971000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":91,"title":["Biological Spiking Synapse Constructed from Solution Processed Bimetal Core\u2013Shell Nanoparticle Based Composites"],"prefix":"10.1002","volume":"14","author":[{"given":"Li","family":"Zhou","sequence":"first","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Yu","family":"Mao","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Ren","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Qin","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shi\u2010Rui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0273-007X","authenticated-orcid":false,"given":"Ye","family":"Zhou","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiufan","family":"Liao","sequence":"additional","affiliation":[{"name":"Shenzhen Key Laboratory of Laser Engineering College of Optoelectronic Engineering Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Jia","family":"Zeng","sequence":"additional","affiliation":[{"name":"Shenzhen Key Laboratory of Laser Engineering College of Optoelectronic Engineering Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haiquan","family":"Shan","sequence":"additional","affiliation":[{"name":"Department of Chemistry South University of Science and Technology of China  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongxiang","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Chemistry South University of Science and Technology of China  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingjing","family":"Fu","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoli","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyu","family":"Lv","sequence":"additional","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Su\u2010Ting","family":"Han","sequence":"additional","affiliation":[{"name":"College of Electronic Science &amp; Technology Shenzhen University  Shenzhen 518060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vellaisamy A. 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