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Here a two\u2010step procedure for constructing hollow Rh nanospheres (Rh H\u2010NSs) with clean surface is described. By selectively removing the surfactant and Au core of Au\u2010core@Rh\u2010shell nanostructures (Au@Rh NSs), the surface\u2010cleaned Rh H\u2010NSs are obtained, which contain abundant porous channels and large specific surface area. The as\u2010prepared Rh H\u2010NSs exhibit enhanced inherent activity for the methanol oxidation reaction (MOR) compared to state\u2010of\u2010the\u2010art Pt nanoparticles in alkaline media. Further electrochemical experiments show that Rh H\u2010NSs also have high activity for the electrooxidation of formaldehyde and formate (intermediate species in the course of the MOR) in alkaline media. Unfortunately, Rh H\u2010NSs have low electrocatalytic activity for the ethanol and 1\u2010propanol oxidation reactions in alkaline media. All electrochemical results indicate that the order of electrocatalytic activity of Rh H\u2010NSs for alcohol oxidation reaction is methanol (C<jats:sub>1<\/jats:sub>) &gt; ethanol (C<jats:sub>2<\/jats:sub>) &gt; 1\u2010propanol (C<jats:sub>3<\/jats:sub>). This work highlights the synthesis route of Rh hollow nanostructures, and indicates the promising application of Rh nanostructures in alkaline direct methanol fuel cells.<\/jats:p>","DOI":"10.1002\/smll.201801239","type":"journal-article","created":{"date-parts":[[2018,6,8]],"date-time":"2018-06-08T05:45:21Z","timestamp":1528436721000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":103,"title":["Selective Etching Induced Synthesis of Hollow Rh Nanospheres Electrocatalyst for Alcohol Oxidation Reactions"],"prefix":"10.1002","volume":"14","author":[{"given":"Yong\u2010Qiang","family":"Kang","sequence":"first","affiliation":[{"name":"Key Laboratory of Macromolecular Science of Shaanxi Province Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) Shaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and Engineering Shaanxi Normal University  West Chang'an Avenue, Chang'an District Xi'an 710119 P. 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