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However, their sensing application has not been fully established yet. Herein, a rare example of using flexible MOF\u2010based MMMs as a fluorescent turn\u2010on sensor for the detection of hydrogen sulfide (H<jats:sub>2<\/jats:sub>S) is reported. These MOF\u2010based MMMs are readily prepared by mixing a highly stable aluminum\u2010based nano\u2010MOF (Al\u2010MIL\u201053\u2010NO<jats:sub>2<\/jats:sub>) into poly(vinylidene fluoride) with high loadings up to 70%. Unlike the intrinsic fragility and poor processability of pure\u2010MOF membranes, these MMMs exhibit desirable flexibility and processability that are more suitable for practical sensing applications. The uniform distribution of Al\u2010MIL\u201053\u2010NO<jats:sub>2<\/jats:sub> particles combined with the permanent pores of MOFs enable these MMMs to show good water permeation flux and consequently have a full contact between the analyte and MOFs. The developed MMM sensor (70% MOF loading) thus shows a highly remarkable detection selectivity and sensitivity for H<jats:sub>2<\/jats:sub>S with an exceptionally low detection limit around 92.31 \u00d7 10<jats:sup>\u22129<\/jats:sup><jats:sc>m<\/jats:sc>, three orders of magnitude lower than the reported powder\u2010form MOFs. This work demonstrates that it is feasible to develop flexible luminescent MOF\u2010based MMMs as a novel platform for chemical sensing applications.<\/jats:p>","DOI":"10.1002\/smll.201801563","type":"journal-article","created":{"date-parts":[[2018,7,26]],"date-time":"2018-07-26T11:22:13Z","timestamp":1532604133000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":118,"title":["Flexible Metal\u2013Organic Framework\u2010Based Mixed\u2010Matrix Membranes: A New Platform for H<sub>2<\/sub>S Sensors"],"prefix":"10.1002","volume":"14","author":[{"given":"Xin","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silicon Materials Cyrus Tang Center for Sensor Materials and Applications School of Materials Science and Engineering Zhejiang University  Hangzhou 310027 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