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On the other hand, the presence of additional reversible conversion reactions makes the metal compounds the preferred anode materials over carbon. However, conductivity and crystallinity of such materials often play the pivotal role in this regard. To address these issues, atomic layer deposited double\u2010anion\u2010based ternary zinc oxysulfide (ZnOS) thin films as an anode material in SIBs are reported. Electrochemical studies are carried out with different O\/(O+S) ratios, including O\u2010rich and S\u2010rich crystalline ZnOS along with the amorphous phase. Amorphous ZnOS with the O\/(O+S) ratio of \u22480.4 delivers the most stable and considerably high specific (and volumetric) capacities of 271.9 (\u22481315.6 mAh cm<jats:sup>\u22123<\/jats:sup>) and 173.1 mAh g<jats:sup>\u22121<\/jats:sup> (\u2248837.7 mAh cm<jats:sup>\u22123<\/jats:sup>) at the current densities of 500 and 1000 mA g<jats:sup>\u22121<\/jats:sup>, respectively. A dominant capacitive\u2010controlled contribution of the amorphous ZnOS anode indicates faster electrochemical reaction kinetics. An electrochemical reaction mechanism is also proposed via X\u2010ray photoelectron spectroscopy analyses. A comparison of the cycling stability further establishes the advantage of this double\u2010anion\u2010based material over pristine ZnO and ZnS anodes.<\/jats:p>","DOI":"10.1002\/smll.201900595","type":"journal-article","created":{"date-parts":[[2019,8,2]],"date-time":"2019-08-02T14:29:32Z","timestamp":1564756172000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Revealing the Simultaneous Effects of Conductivity and Amorphous Nature of Atomic\u2010Layer\u2010Deposited Double\u2010Anion\u2010Based Zinc Oxysulfide as Superior Anodes in Na\u2010Ion Batteries"],"prefix":"10.1002","volume":"15","author":[{"given":"Soumyadeep","family":"Sinha","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering and Optoelectronics Convergence Research Center Chonnam National University  Gwangju 61186 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pravin 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