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The canonical surface modification approach can improve the stability to a certain extent; however, it fails to resolve the key bottlenecks. The preparation of Li(Ni\n                    <jats:sub>0.4<\/jats:sub>\n                    Co\n                    <jats:sub>0.2<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    )\n                    <jats:sub>1\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Ti\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    on the surface of LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    particles with a coprecipitation method is reported. After sintering, Ti diffuses into the interior and mainly distributes along surface and grain boundaries. A strong surface and grain boundary strengthening are simultaneously achieved. The pristine particles are fully pulverized into first particles due to mechanical instability and high strains, which results in serious capacity fading. In contrast, the strong surface and the grain boundary strengthening can maintain the structural integrity, and therefore significantly improve the cycle stability. A general and simple strategy for the design of high\u2010performance Ni\u2010rich LiNi\n                    <jats:sub>1\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sub>\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    Co\n                    <jats:sub>x<\/jats:sub>\n                    Mn\n                    <jats:sub>y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    cathode is provided and is applicable to surface modification and grain\u2010boundary regulation of other advanced cathodes for batteries.\n                  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