{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T21:08:39Z","timestamp":1761340119986,"version":"3.41.2"},"reference-count":35,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2020,9,6]],"date-time":"2020-09-06T00:00:00Z","timestamp":1599350400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001459","name":"Ministry of Education - Singapore","doi-asserted-by":"publisher","award":["RG6\/18"],"award-info":[{"award-number":["RG6\/18"]}],"id":[{"id":"10.13039\/501100001459","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2020,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A combined photothermal\u2010catalytic system that contains a single active element, without using different entities for separate roles (catalytic vs photothermal), is designed here for efficient catalytic reactions. Herein, ultrathin (sub\u20106 nm) rectangular\u2010like KNdF<jats:sub>4<\/jats:sub> nanoplates consisting of 3\u20134 unit cell layers are prepared where the Nd<jats:sup>3+<\/jats:sup> ions act as a Lewis acid catalyst. In addition, the nanoplates undergo light\u2010to\u2010heat conversion when irradiated with NIR light due to cross\u2010relaxation and nonradiative relaxation processes from excited Nd<jats:sup>3+<\/jats:sup>. The cyanosilylation of a series of ketones is performed using the nano\u2010hotplate catalysts to give near quantitative yields of the cyanohydrin trimethylsilyl ethers. This is because of the high surface area\u2010to\u2010volume ratio of the thin nanoplates that provides a large number of surface Nd<jats:sup>3+<\/jats:sup> catalytic sites for reaction. The reaction kinetics are enhanced by the photothermal effect, leading to the observed &gt; 10\u2010fold increase in product yields.<\/jats:p>","DOI":"10.1002\/smll.202002698","type":"journal-article","created":{"date-parts":[[2020,9,8]],"date-time":"2020-09-08T13:01:48Z","timestamp":1599570108000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Ultrathin Near\u2010Infrared Light Activated Nano\u2010Hotplate Catalyst"],"prefix":"10.1002","volume":"16","author":[{"given":"Xiangyang","family":"Wu","sequence":"first","affiliation":[{"name":"Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  21 Nanyang Link Singapore 637371 Singapore"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0290-4882","authenticated-orcid":false,"given":"Edwin K. L.","family":"Yeow","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  21 Nanyang Link Singapore 637371 Singapore"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,9,6]]},"reference":[{"key":"e_1_2_4_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC02149A"},{"key":"e_1_2_4_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b12230"},{"key":"e_1_2_4_1_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01741"},{"key":"e_1_2_4_1_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201510655"},{"key":"e_1_2_4_1_5","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201903847"},{"key":"e_1_2_4_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12074"},{"key":"e_1_2_4_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE02790K"},{"key":"e_1_2_4_2_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02532"},{"key":"e_1_2_4_2_4","doi-asserted-by":"publisher","DOI":"10.1039\/C7QM00337D"},{"key":"e_1_2_4_2_5","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11355-x"},{"key":"e_1_2_4_2_6","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201902576"},{"key":"e_1_2_4_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b02830"},{"key":"e_1_2_4_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp000679t"},{"key":"e_1_2_4_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00340-010-4300-7"},{"key":"e_1_2_4_4_2","doi-asserted-by":"crossref","first-page":"847","DOI":"10.1039\/c2nr32203j","volume":"4","author":"Wawrzynczyk D.","year":"2012","journal-title":"Nanoscale"},{"key":"e_1_2_4_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR04178H"},{"key":"e_1_2_4_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn203293t"},{"key":"e_1_2_4_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl201400z"},{"volume-title":"Lewis Acids in Organic Synthesis","year":"2000","author":"Shibasaki M.","key":"e_1_2_4_7_1"},{"key":"e_1_2_4_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03736G"},{"key":"e_1_2_4_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic300816r"},{"key":"e_1_2_4_8_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic3008365"},{"key":"e_1_2_4_8_4","doi-asserted-by":"publisher","DOI":"10.1021\/om500924q"},{"key":"e_1_2_4_8_5","doi-asserted-by":"publisher","DOI":"10.1080\/00397910500212957"},{"key":"e_1_2_4_9_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0611309104"},{"key":"e_1_2_4_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200800183"},{"key":"e_1_2_4_9_3","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC00826D"},{"key":"e_1_2_4_9_4","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0690(200210)2002:19<3243::AID-EJOC3243>3.0.CO;2-E"},{"key":"e_1_2_4_9_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300604"},{"key":"e_1_2_4_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/b909145a"},{"key":"e_1_2_4_11_1","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1134\/S1063774515060346","volume":"61","author":"Sorokin N. I.","year":"2016","journal-title":"Crystallogr. Rep."},{"key":"e_1_2_4_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja108948z"},{"key":"e_1_2_4_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/la201910t"},{"key":"e_1_2_4_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05486"},{"key":"e_1_2_4_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE02660E"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fsmll.202002698","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202002698","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202002698","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202002698","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,5]],"date-time":"2023-09-05T10:28:05Z","timestamp":1693909685000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202002698"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9,6]]},"references-count":35,"journal-issue":{"issue":"40","published-print":{"date-parts":[[2020,10]]}},"alternative-id":["10.1002\/smll.202002698"],"URL":"https:\/\/doi.org\/10.1002\/smll.202002698","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"type":"print","value":"1613-6810"},{"type":"electronic","value":"1613-6829"}],"subject":[],"published":{"date-parts":[[2020,9,6]]},"assertion":[{"value":"2020-04-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-09-06","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2002698"}}