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Herein, using the phase transformation of uniform rhombi dodecahedron ZIF\u201067, hollow nano\u2010shell with a well\u2010defined morphology is successfully prepared. Particularly, the iron\u2010oxygen complex, that is formed by the interaction between TCPP\u2010Fe\/Cu (TCPP = tetrakis(4\u2010carboxyphenyl)\u2010porphyrin) and oxygen, can be acted as an ideal proton acceptor for practical organic reactions. Considering the unique adaptability of hollow ZIFs (named HZ) to the transformation of encapsulated TCPP\u2010Fe\/Cu bimetallic catalytic active sites, a heterogeneous catalyst (defined as HZ@TCPP\u2010Fe\/Cu) through morphology\u2010controlled thermal transformation and rear assemble processes is designed and constructed. Under heterogeneous conditions, HZ@TCPP\u2010Fe\/Cu serves as a multifunctional molecular selector to promote the oxidative dehydrogenation of different aromatic hydrazide derivatives with high selectivity toward primary carbon among primary, secondary, and tertiary carbons that are unachievable by other traditional homogeneous catalysts. The high catalytic activity, selectivity, and recyclability of the catalyst proposed here are attractive advantages for an alternative route to the environmentally benign transformation of aromatic hydrazides to aromatic azobenzene.<\/jats:p>","DOI":"10.1002\/smll.202004679","type":"journal-article","created":{"date-parts":[[2020,11,18]],"date-time":"2020-11-18T20:43:14Z","timestamp":1605732194000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Encapsulation of Porphyrin\u2010Fe\/Cu Complexes into Coordination Space for Enhanced Selective Oxidative Dehydrogenation of Aromatic Hydrazides"],"prefix":"10.1002","volume":"16","author":[{"given":"Dongxu","family":"Zhang","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Molecular Optoelectronic Science Department of Chemistry School of Science Tianjin University  Tianjin 300072 P. R. 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