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Herein, sulfurized carbon nanotube@aminophenol\u2010formaldehyde (SC@A) with covalently linked short\u2010chain sulfurs is firstly synthesized by in situ polymerization of aminophenol\u2010formaldehyde (AF) on the surface of carbon nanotubes (CNTs) followed by acetone etching and inverse sulfurization processes, forming mesoporous yolk\u2010shell organosulfur nanotubes with abundant internal joints between the yolk of CNTs and the shell of sulfurized AF for the first time. In situ Raman spectra, in situ XRD patterns, and ex situ XPS spectra verify that the covalent short\u2010chain sulfurs bring about a reversible solid\u2010solid conversion process of sulfur, thoroughly avoiding the shuttle effect. The mesoporous yolk\u2010shell structure with abundant internal joints can effectively accommodate the volume change, fully expose active sites and efficiently improve the transport of electrons and lithium ions, thus highly promoting the solid\u2013solid electrochemical reaction kinetics. Therefore, the SC@A cathode exhibits a superior specific capacity of 841\u00a0mAh g<jats:sup>\u22121<\/jats:sup> and a capacity decay of 0.06% per cycle within 500 cycles at a large current density of 5.0 C.<\/jats:p>","DOI":"10.1002\/smll.202101857","type":"journal-article","created":{"date-parts":[[2021,8,5]],"date-time":"2021-08-05T06:42:50Z","timestamp":1628145770000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Mesoporous Yolk\u2010Shell Structured Organosulfur Nanotubes with Abundant Internal Joints for High\u2010Performance Lithium\u2013Sulfur Batteries by Kinetics Acceleration"],"prefix":"10.1002","volume":"17","author":[{"given":"Wei","family":"Chang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing 100029 China"},{"name":"Beijing Key Laboratory of Advanced 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