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However, the uncontrollable dendrites growth and the negligible subzero temperature performance impede the batteries practical applications. Herein, it is demonstrated that dimethyl sulfoxide (DMSO) is an effective additive in ZnSO<jats:sub>4<\/jats:sub> electrolyte for side reactions and dendrites suppression by regulating the Zn\u2010ion solvation structure and inducing the Zn<jats:sup>2+<\/jats:sup> to form the more electrochemical stable (002) basal plane, via the higher absorption energy of DMSO with Zn<jats:sup>2+<\/jats:sup> and (002) plane. Moreover, the stable reconstructed hydrogen bonds between DMSO and H<jats:sub>2<\/jats:sub>O dramatically lower the freezing point of the electrolyte, which significantly increases the ionic conductivity and cycling performance of the aqueous batteries at subzero temperatures. As a consequence, the symmetrical Zn\/Zn cell can be kept stable for more than 2100 h at 20\u00a0\u00b0C and 1200 h at \u221220\u00a0\u00b0C without dendrite and by\u2010products formation. The Zn\/MnO<jats:sub>2<\/jats:sub> batteries can perform steadily for more than 3000 cycles at 20\u00a0\u00b0C and 300 cycles at \u221220\u00a0\u00b0C. This work provides a facile and feasible strategy on designing high performance and dendrite free aqueous Zn\u2010ion batteries for various temperatures.<\/jats:p>","DOI":"10.1002\/smll.202103195","type":"journal-article","created":{"date-parts":[[2021,9,16]],"date-time":"2021-09-16T06:50:40Z","timestamp":1631775040000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":419,"title":["Immunizing Aqueous Zn Batteries against Dendrite Formation and Side Reactions at Various Temperatures via Electrolyte Additives"],"prefix":"10.1002","volume":"17","author":[{"given":"Doudou","family":"Feng","sequence":"first","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry Chemical Engineering and Biotechnology Donghua University  Shanghai 201620 P. R. 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