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Here, antibacterial textiles are fabricated by in situ growing oxygen vacancies (OVs) BiOBr on the surface of Ti<jats:sub>3<\/jats:sub>C<jats:sub>2<\/jats:sub> nanosheets followed by in situ polymerization of polypyrrole (ppy). The formed Schottky heterojunction containing OVs of Ti<jats:sub>3<\/jats:sub>C<jats:sub>2<\/jats:sub>\/BiOBr effectively enhance the transfer and separation of photogenerated carriers, inhibit the recombination, and decrease the band gap by introducing defect level, which significantly improve the photocatalytic activity, leading to higher reactive oxygen species (ROS) under light irradiation. Therefore, the antibacterial efficacy of textiles reaches up to 98.64% against <jats:italic>Staphylococcus aureus<\/jats:italic> and 99.89% against <jats:italic>Escherichia coli<\/jats:italic> with the assistance of hyperthermia under light irradiation for 15\u00a0min. This work provides insights for designing photo\u2010excited antibacterial textiles by interfacial construction based on Schottky junctions and OVs in the incorporated nanomaterials.<\/jats:p>","DOI":"10.1002\/smll.202104448","type":"journal-article","created":{"date-parts":[[2021,11,29]],"date-time":"2021-11-29T06:39:37Z","timestamp":1638167977000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":57,"title":["Oxygen Vacancies\u2010Rich Heterojunction of Ti<sub>3<\/sub>C<sub>2<\/sub>\/BiOBr for Photo\u2010Excited Antibacterial Textiles"],"prefix":"10.1002","volume":"18","author":[{"given":"Jianfang","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lili","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangmei","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Life Science and Health Engineering Hebei University of Technology  Xiping Avenue 5340, Beichen District Tianjin 300401 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering State Key Laboratory for Turbulence and Complex System Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanqin","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyong","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Life Science and Health Engineering Hebei University of Technology  Xiping Avenue 5340, Beichen District Tianjin 300401 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenduo","family":"Cui","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengli","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1270-1870","authenticated-orcid":false,"given":"Shuilin","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering the Key Laboratory of Advanced Ceramics and Machining Technology by the Ministry of Education of China Tianjin University  Weijin Avenue 92# Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,11,28]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhin.2007.03.026"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/jhm.864"},{"key":"e_1_2_8_3_1","unstructured":"G.Jacob Uniforms and Workwear: An Evidence Base for Developing Local Policy National Health Service Department of Health Policy2007."},{"key":"e_1_2_8_4_1","volume-title":"Scottish Government Health Directorates. 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