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Here, a combined theoretical and experimental spectro\u2010microscopy approach is used to show that the charge transfer occurring at the interface between nickel tetraphenyl porphyrins and copper changes both spin and oxidation states of the Ni ion from [Ni(II), <jats:italic>S<\/jats:italic>\u00a0<jats:bold>=<\/jats:bold>\u00a00] to [Ni(I), <jats:italic>S<\/jats:italic>\u00a0<jats:bold>=<\/jats:bold>\u00a01\/2]. The chemically active Ni(I), even in a buried multilayer system, can be functionalized with nitrogen dioxide, allowing a selective tuning of the electronic properties of the Ni center that is switched to a [Ni(II), <jats:italic>S<\/jats:italic> = 1] state. While Ni acts as a reversible spin switch, it is found that the electronic structure of the macrocycle backbone, where the frontier orbitals are mainly localized, remains unaffected. These findings pave the way for using the present porphyrin\u2010based system as a platform for the realization of multifunctional devices where the magnetism and the optical\/transport properties can be controlled simultaneously by independent stimuli.<\/jats:p>","DOI":"10.1002\/smll.202104779","type":"journal-article","created":{"date-parts":[[2021,10,16]],"date-time":"2021-10-16T16:06:32Z","timestamp":1634400392000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Room\u2010Temperature On\u2010Spin\u2010Switching and Tuning in a Porphyrin\u2010Based Multifunctional Interface"],"prefix":"10.1002","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4686-5360","authenticated-orcid":false,"given":"Henning Maximilian","family":"Sturmeit","sequence":"first","affiliation":[{"name":"TU Dortmund University Experimental Physics VI  44227 Dortmund 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