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The global demand for high\u2010performance and recyclable face masks is increasing dramatically, especially during the COVID\u201019 pandemic. However, present masks suffer from low\u2010efficiency interception of PM\n                    <jats:sub>0.3<\/jats:sub>\n                    \/pathogen, limited air permeability, and incapacity to reuse and recycle. Here, multi\u2010scale nanoarchitectured nanofiber\/carbon nanotube (NF\/CNT) networks are constructed by a needleless\u2010electrospinning\/spraying\u2010netting strategy, enabling well\u2010dispersed CNT networks (diameter\n                    <jats:bold>\u2248<\/jats:bold>\n                    25\u00a0nm) welded on charged nanofibrous scaffolds (diameter\n                    <jats:bold>&gt;<\/jats:bold>\n                    100\u00a0nm)\u00a0layer by layer. The optimized NF\/CNT networks possess a fluffy structure with narrow\u2010distribution small pores (size\n                    <jats:bold>\u2248<\/jats:bold>\n                    400\u00a0nm), \u201cfree molecular flow\u201d behavior, and electrostatic adsorption property, thereby exhibiting high filtration efficiency (\n                    <jats:bold>&gt;<\/jats:bold>\n                    99.994% PM\n                    <jats:sub>0.3<\/jats:sub>\n                    removal) and low resistance (\n                    <jats:bold>&lt;<\/jats:bold>\n                    0.05% atmosphere pressure). Furthermore, they demonstrate reliable and ultra\u2010fast photothermal\u2010driven self\u2010sterilization (\n                    <jats:bold>&gt;<\/jats:bold>\n                    99.986% in 5\u00a0min) under 1 sun and electrothermal\u2010driven self\u2010sterilization (\n                    <jats:bold>&gt;<\/jats:bold>\n                    99.9999% in 2\u00a0min) in sunless scenes owing to their unique nanoarchitecture. Most importantly, the abandoned NF\/CNT filters can be fully recycled as high\u2010performance solar vapor generators to desalinate seawater (3.56 L m\n                    <jats:sup>\u22122<\/jats:sup>\n                    d\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work offers a fascinating solution to reduce disease transmission, resource consumption, and environmental burdens.\n                  <\/jats:p>","DOI":"10.1002\/smll.202105570","type":"journal-article","created":{"date-parts":[[2021,11,30]],"date-time":"2021-11-30T17:10:29Z","timestamp":1638292229000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":68,"title":["Multi\u2010Scale Nanoarchitectured Fibrous Networks for High\u2010Performance, Self\u2010Sterilization, and Recyclable Face Masks"],"prefix":"10.1002","volume":"18","author":[{"given":"Jian","family":"Xiong","sequence":"first","affiliation":[{"name":"Key Laboratory of Textile Science and Technology of Ministry of Education College of Textiles Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ailin","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Textile Science and Technology of Ministry of Education College of Textiles Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Textile Science and Technology of Ministry of Education College of Textiles Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6958-3131","authenticated-orcid":false,"given":"Liming","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Textile Science and Technology of Ministry of Education College of Textiles Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohong","family":"Qin","sequence":"additional","affiliation":[{"name":"Key Laboratory of Textile Science and Technology of Ministry of Education College of Textiles Donghua University  Shanghai 201620 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