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However, the materials cannot be commercialized for application so far. The crucial problem is the releasing of lattice oxygen at high voltage and resulting consequence, such as decomposition of electrolyte, irreversible phase transition of crystal structure, capacity degradation, and voltage decay. Therefore, capturing active\u2010oxygen and further constructing a cathode\u2010electrolyte\u2010interface (CEI) protective layer via the scavenging effects should be a fundamental step to solve these issues. Herein, \u03b2\u2010carotene with antioxidant properties is used as a scavenging molecule to achieve this goal. The control of active oxygen species effectively alleviates the decomposition of carbonate electrolyte under high voltage. The introduction of \u03b2\u2010carotene additives can also be adjusted in situ to generate a customized CEI film, which is a double\u2010layer structure with external organic components and internal inorganic components. Moreover, the \u03b2\u2010carotene\u2010containing electrolyte system exhibits better thermal stability. Benefited from these, Lithium\u2010rich cathode of \u03b2\u2010carotene\u2010containing electrolyte shows outstanding long\u2010life cycle stability, with 93.4% capacity retention rate after 200 cycles at 1 C; this electrochemical stability is superior to other electrolyte additive systems reported at present.<\/jats:p>","DOI":"10.1002\/smll.202106072","type":"journal-article","created":{"date-parts":[[2021,12,4]],"date-time":"2021-12-04T08:09:11Z","timestamp":1638605351000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["An Active\u2010Oxygen\u2010Scavenging Oriented Cathode\u2010Electrolyte\u2010Interphase for Long\u2010Life Lithium\u2010Rich Cathode Materials"],"prefix":"10.1002","volume":"18","author":[{"given":"Yajing","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering 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