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Sodium\u2013sulfur (Na\u2013S) batteries present higher feasibility of long\u2010term development than lithium\u2013sulfur (Li\u2013S) batteries in technoeconomic and geopolitical terms. Both lithium and sodium are alkali metal elements with body\u2010centered cubic structures, leading to similar physical and chemical properties and exposing similar issues when employed as the anode in metal\u2013sulfur batteries. Indeed, some inspiration for mechanism researches and strategies in Na\u2013S systems comes from the more mature Li\u2013S systems. However, the dissimilarities in microscopic characteristics determine that Na\u2013S is not a direct Li\u2013S analogue. Herein, the daunting challenges derived by the differences of fundamental characteristics in Na\u2013S and Li\u2013S systems are discussed. And the corresponding strategies in Na\u2013S batteries are reviewed. 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