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Herein, cost\u2010effective and highly conductive few\u2010layer ferric and nickel chloride co\u2010intercalated graphite intercalation compounds (FeCl\n                    <jats:sub>3<\/jats:sub>\n                    \u2010NiCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010GIC) are designed as bifunctional oxygen catalysts for ZAB. The optimized few\u2010layer FeCl\n                    <jats:sub>3<\/jats:sub>\n                    \u2010NiCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010GIC catalyst exhibits a small overpotential of 276\u00a0mV at 10\u00a0mA cm\n                    <jats:sup>\u20132<\/jats:sup>\n                    for the OER and achieves a high onset potential of 0.89\u00a0V for the ORR. The theoretical analysis demonstrates the electron\u2010rich state on the carbon layers of FeCl\n                    <jats:sub>3<\/jats:sub>\n                    \u2010NiCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010GIC during the catalytic process favors the kinetics of electron transfer and lowers the absorption energy barriers for intermediates. Impressively, the ZAB assembled with few\u2010layer FeCl\n                    <jats:sub>3<\/jats:sub>\n                    \u2010NiCl\n                    <jats:sub>2<\/jats:sub>\n                    \u2010GIC catalyst displays a 160 h cycling stability and a high energy efficiency of 72.6%. This work also suggests the possibility of utilizing layer electronic structure regulation on graphite intercalation compounds as effective bifunctional catalysts for ZABs.\n                  <\/jats:p>","DOI":"10.1002\/smll.202107667","type":"journal-article","created":{"date-parts":[[2022,1,31]],"date-time":"2022-01-31T04:35:36Z","timestamp":1643603736000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Manipulating the Electronic Structure of Graphite Intercalation Compounds for Boosting the Bifunctional Oxygen Catalytic Performance"],"prefix":"10.1002","volume":"18","author":[{"given":"Licheng","family":"Wei","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufei","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minghui","family":"Ye","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2434-760X","authenticated-orcid":false,"given":"Cheng Chao","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 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