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The low\u2010energy\u2010density might persist with low\u2010voltage cathode material; hence, high\u2010voltage cathode material development is required. While LiNi\n                    <jats:sub>0.5<\/jats:sub>\n                    Mn\n                    <jats:sub>1.5<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (LNM) has been considered a promising high\u2010voltage cathode material. This study investigates the electrochemical properties of LNM thin films based on the correlation between the ordering of cations (Ni and Mn) and oxygen vacancies (\n                    <jats:italic>V<\/jats:italic>\n                    <jats:sub>O<\/jats:sub>\n                    ). The authors find that the cations\u2019 order changes from a disordered structure to an ordered structure with an increased oxygen flow rate during deposition. The optimized LNM fabricated using a 60:40 ratio of Ar to O\n                    <jats:sub>2<\/jats:sub>\n                    exhibits the highest rate capability (321.4 mAh cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    @ 20 C) and most prolonged cycle performance for 500 cycles. The role of\n                    <jats:italic>V<\/jats:italic>\n                    <jats:sub>O<\/jats:sub>\n                    within the LNM structure and the lower activation energy of ordered LNM compared to disordered LNM through first\u2010principles density functional theory calculations is elucidated. The superior electrochemical performance (276.9\u00a0mAh\u00a0cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    @ 0.5 C) and high cyclic performance (at 93.9%, 500 cycles) are corroborated by demonstrating flexible ASSTFB cells using LiPON solid\u2010state electrolyte and thin\u2010film Li anode. This work paves the way for future research on the fabrication of high\u2010performance flexible ASSTFBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.202201134","type":"journal-article","created":{"date-parts":[[2022,5,2]],"date-time":"2022-05-02T06:57:45Z","timestamp":1651474665000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Investigation of Ordering on Oxygen\u2010Deficient LiNi\n                    <sub>0.5<\/sub>\n                    Mn\n                    <sub>1.5<\/sub>\n                    O\n                    <sub>4\u2010\u03b4<\/sub>\n                    Thin Films for Boosting Electrochemical Performance in All\u2010Solid\u2010State Thin\u2010Film Batteries"],"prefix":"10.1002","volume":"18","author":[{"given":"Jong Heon","family":"Kim","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Chungnam National University  Daejeon 34134 Republic of 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Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4286-7027","authenticated-orcid":false,"given":"Hyun\u2010Suk","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Chungnam National University  Daejeon 34134 Republic of 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