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A developed pretreatment methodology is employed to prefer the crystal plane of polycrystalline Zn and create 3.26\u00a0\u00b5m protective coatings mainly consisting of organic polymers and zinc salts on Zn foils (ROZ@Zn). In this process, Zn metal exhibits a surface\u2010preferred (001) crystal plane proved by electron backscattered diffraction. Preferred (001) crystal planes and ROZ coatings can regulate Zn<jats:sup>2+<\/jats:sup> diffusion, promote flat growth of Zn, and prevent side reactions. As a result, ROZ@Zn symmetrical cells exhibit superior plating\/stripping performance over 1300\u00a0h. Impressively, it is significantly prolonged over 40\u00a0times in comparison to the bare Zn symmetric cell at 5\u00a0mA\u00a0cm<jats:sup>\u20102<\/jats:sup>. Moreover, Zn\/\/MnO<jats:sub>2<\/jats:sub>\u00a0button cells have a high capacity retention of 96.3% after 1600\u00a0cycles and pouch cells have a high capacity 122\u00a0mAh\u00a0g<jats:sup>\u20101<\/jats:sup>\u00a0after 200\u00a0cycle at 5\u00a0C. This work provides inspiration for high stable aqueous Zn metal batteries using the developed metal pretreatment of anticorrosion, which will be a viable, low\u2010cost, and efficient technology. More interesting, it demonstrates the availability of reconstructing crystal planes by the largely heterogeneous reaction activation of the different crystal planes to H<jats:sup>+<\/jats:sup>.<\/jats:p>","DOI":"10.1002\/smll.202201443","type":"journal-article","created":{"date-parts":[[2022,5,3]],"date-time":"2022-05-03T05:18:59Z","timestamp":1651555139000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Crystal Plane Reconstruction and Thin Protective Coatings Formation for Superior Stable Zn Anodes Cycling 1300 h"],"prefix":"10.1002","volume":"18","author":[{"given":"Mengke","family":"Liu","sequence":"first","affiliation":[{"name":"Hefei National Laboratory for Physical Science at Microscale and School of Chemistry and Materials Science University of Science and Technology of China  Hefei 230026 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