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To address these obstacles, a bio\u2010inspired approach, which exploits the moderate metabolic energy of cell systems and the amphiphilic nature of plasma membranes, is employed to construct a bio\u2010inspired hydrophobic conductive poly(3,4\u2010ethylenedioxythiophene) film decorating \u03b1\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    cathode. Like plasma membranes, the bio\u2010inspired film can \u201cselectively\u201d boost Zn\n                    <jats:sup>2+<\/jats:sup>\n                    migration with a lower energy barrier and maintain the integrity of the entire cathode. Electrochemical reaction kinetics analysis and theoretical calculations reveal that the bio\u2010inspired film can significantly improve the electrical conductivity of the electrode, endow the cathode\u2013electrolyte interface with engineered hydrophobicity, and enhance the desolvation behavior of hydrated Zn\n                    <jats:sup>2+<\/jats:sup>\n                    . This results in an enhanced ion diffusion rate and minimized cathode dissolution, thereby boosting the overall interfacial reaction kinetics and cathode stability. Owing to these intriguing merits, the composite cathode can demonstrate remarkable cycling stability and rate performance in comparison with the pristine MnO\n                    <jats:sub>2<\/jats:sub>\n                    cathode. Based on the bio\u2010inspired design philosophy, this work can provide a novel insight for future research on promoting the interfacial reaction kinetics and electrode stability for various battery systems.\n                  <\/jats:p>","DOI":"10.1002\/smll.202201732","type":"journal-article","created":{"date-parts":[[2022,5,13]],"date-time":"2022-05-13T07:39:24Z","timestamp":1652427564000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":95,"title":["Construction of Bio\u2010inspired Film with Engineered Hydrophobicity to Boost Interfacial Reaction Kinetics of Aqueous Zinc\u2013Ion Batteries"],"prefix":"10.1002","volume":"18","author":[{"given":"Qianzhi","family":"Gou","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Low\u2010grade Energy Utilization Technologies and Systems CQU\u2010NUS Renewable Energy Materials &amp; Devices Joint Laboratory School of Energy &amp; Power Engineering Chongqing University Chongqing 400044 P. 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