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Herein, inspired by sodium hyaluronate (SH) biomolecules in living organisms featured with the functions of water retention, ion\u2010transport regulation, and film\u2010formation, the SH working as a dynamic and self\u2010adaptive \u201cmask\u201d is proposed to stabilize Zn anode. Benefiting from the abundant functional groups with high hydrophilicity and zincophilicity, SH molecule can constrain active water molecules on the Zn\u2010electrolyte interface and participate in Zn<jats:sup>2+<\/jats:sup> solvation structure to suppress parasitic reactions. Furthermore, the dynamical adsorption of SH with high\u2010density negative charge on the Zn surface could serve as Zn<jats:sup>2+<\/jats:sup> reservoirs to guide uniform Zn deposition. Consequently, stable Zn plating and an ultrahigh cumulative plating capacity (CPC) of 4.8 Ah cm<jats:sup>\u20102<\/jats:sup> are achieved even at 20 mA cm<jats:sup>\u20102<\/jats:sup> (20 mAh cm<jats:sup>\u20102<\/jats:sup>) in a Zn||Zn symmetric battery, reaching a record level in AZMBs. In addition, the Zn||\u03b2\u2010MnO<jats:sub>2<\/jats:sub> full battery exhibits a substantially improved cycle stability. This work presents a route to realize a highly reversible and stable Zn metal anode by learning from nature.<\/jats:p>","DOI":"10.1002\/smll.202202214","type":"journal-article","created":{"date-parts":[[2022,5,28]],"date-time":"2022-05-28T02:00:00Z","timestamp":1653703200000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Dynamic Biomolecular \u201cMask\u201d Stabilizes Zn Anode"],"prefix":"10.1002","volume":"18","author":[{"given":"Yanmei","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering University of Science and Technology Beijing  Beijing 100083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry Beijing Advanced Innovation Center for Biomedical Engineering Beihang University  Beijing 100191 P. R. 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