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Herein, for the first time, <jats:sc>l<\/jats:sc>\u2010cysteine (Cys) is employed to serve as an electrolyte additive for stabilizing the Zn\/electrolyte interface. It is revealed that Cys additives tend to initially approach the Zn surface and then decompose into multiple effective components for suppressing parasitic reactions and Zn dendrites. As a consequence, Zn|Zn symmetric cells using trace Cys additives (0.83\u00a0m<jats:sc>m<\/jats:sc>) exhibit a steady cycle life of 1600 h, outperforming that of prior studies. Additionally, an average Coulombic efficiency of 99.6% for 250 cycles is also obtained under critical test conditions (10\u00a0mA cm<jats:sup>\u22122<\/jats:sup>\/5 mAh cm<jats:sup>\u22122<\/jats:sup>). Cys additives also enable Zn\u2013V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub> and Zn\u2013MnO<jats:sub>2<\/jats:sub> full cells with an enhanced cycle stability at a low N\/P ratio. More importantly, Cys\/ZnSO<jats:sub>4<\/jats:sub> electrolytes are demonstrated to be still effective after resting for half year, favoring the practical production.<\/jats:p>","DOI":"10.1002\/smll.202203674","type":"journal-article","created":{"date-parts":[[2022,8,9]],"date-time":"2022-08-09T03:01:05Z","timestamp":1660014065000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":48,"title":["Long Shelf\u2010Life Efficient Electrolytes Based on Trace <scp>l<\/scp>\u2010Cysteine Additives toward Stable Zinc Metal Anodes"],"prefix":"10.1002","volume":"18","author":[{"given":"Cong","family":"Huang","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University  Changsha 410082 P. R. 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