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Vanadium\u2010based compounds as a highly promising class of cathode materials still suffer from structural collapse and slow kinetics. Studies have shown that metal ion pre\u2010introduction is an effective method to solve these problems and enhance battery performance. Here, the introduction of Al<jats:sup>3+<\/jats:sup>, Cr<jats:sup>3+<\/jats:sup>, Cu<jats:sup>2+<\/jats:sup> and Fe<jats:sup>3+<\/jats:sup> is found to effectively reduce the migration energy barrier of Zn<jats:sup>2+<\/jats:sup> with the density functional theory calculations, while Al<jats:sup>3+<\/jats:sup> exhibits the best induction effects. Subsequently, Al<jats:sub>0.34<\/jats:sub>V<jats:sub>5<\/jats:sub>O<jats:sub>12<\/jats:sub>\u00b72.4H<jats:sub>2<\/jats:sub>O (AlVOH) nanoribbons are\u00a0synthesized by hydrothermal introduction of Al<jats:sup>3+<\/jats:sup>, demonstratin excellent electrochemical properties (407.8 mAh g<jats:sup>\u20101<\/jats:sup> at 0.2 A g<jats:sup>\u20101<\/jats:sup> and 176.3 mAh g<jats:sup>\u20101<\/jats:sup> after 2000 cycles at 20 A g<jats:sup>\u20101<\/jats:sup>). By further compounding with redox graphene (rGO), AlVOH\/rGO exhibits high capacitance and specific capacity (460.4 mAh g<jats:sup>\u20101<\/jats:sup> at 0.2 A g<jats:sup>\u20101<\/jats:sup> and 180.6 mAh g<jats:sup>\u20101<\/jats:sup> after 2000 cycles at 20 A g<jats:sup>\u20101<\/jats:sup>). In addition, it is found that the introduction of metal ions adjusts the structural water content of the material. Especially, the introduction of Al<jats:sup>3+<\/jats:sup> can increase the interlayer structural water content and make the electrochemical properties of the material more stable.<\/jats:p>","DOI":"10.1002\/smll.202204180","type":"journal-article","created":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T18:40:03Z","timestamp":1665686403000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":64,"title":["Al<sup>3+<\/sup> Introduction Hydrated Vanadium Oxide Induced High Performance for Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"18","author":[{"given":"Jing","family":"Xu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang 830017 P. R. 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