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Herein, by designing a heterojunction, the influence of the electric\u2010field effect on the kinetics of the MoS<jats:sub>2<\/jats:sub> as cathode materials for aqueous Zn\u2010ion batteries (AZIBs) is deeply investigated. The hybrid heterojunction is developed by hydrothermal growth of MoS<jats:sub>2<\/jats:sub> nanosheets on robust titanium\u2010based transition metal compound ([titanium nitride, TiN] and [titanium oxide, TiO<jats:sub>2<\/jats:sub>]) nanowires, denoted TNC@MoS<jats:sub>2<\/jats:sub> and TOC@MoS<jats:sub>2<\/jats:sub> NWS, respectively. Benefiting from the heterostructure architecture and electric\u2010field effect, the TNC@MoS<jats:sub>2<\/jats:sub> electrodes exhibit an impressive rate performance of 200 mAh g<jats:sup>\u22121<\/jats:sup> at 50\u00a0mA g<jats:sup>\u22121<\/jats:sup> and cycling stability over 3000 cycles. Theoretical studies reveal that the hybrid architecture exhibits a large\u2010scale electric\u2010field effect at the interface between TiN and MoS<jats:sub>2<\/jats:sub>, enhances the adsorption energy of Zn\u2010ions, and increases their charge transfer, which leads to accelerated diffusion kinetics. In addition, the electric\u2010field effect can also be effectively applied to TiO<jats:sub>2<\/jats:sub> and MoS<jats:sub>2<\/jats:sub>, confirming that the concept of heterostructures stimulating electric\u2010field can provide a relevant understanding for the architecture of other cathode materials for AZIBs and beyond.<\/jats:p>","DOI":"10.1002\/smll.202204534","type":"journal-article","created":{"date-parts":[[2022,10,13]],"date-time":"2022-10-13T18:41:45Z","timestamp":1665686505000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["Heterostructures Stimulate Electric\u2010Field to Facilitate Optimal Zn<sup>2+<\/sup> Intercalation in MoS<sub>2<\/sub> Cathode"],"prefix":"10.1002","volume":"18","author":[{"given":"Xincheng","family":"Yao","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean 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