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Nonetheless, direct hydrogen release is limited by the ultralow hydrogen evolution rate, while the conventional manner of extra additive and solvent addition for promoting rates greatly deteriorates its hydrogen storage density. Thus, it is still challenging to simultaneously satisfy high\u2010performance hydrogen release and high storage density. Herein, an aerophobicity surface\u2010based gas\u2013liquid interface reaction strategy is proposed, which renders rapid product removal to promote dehydrogenation, fundamentally circumventing the employment of additives and solvents. Accordingly, a hierarchically porous resin\u2010grafted reduced graphene oxide aerogel is designed. It imparts superaerophobic surface to facilitate product detachment from reactive sites, and the structure\u2010oriented interface reaction design provides product diffusion channels and reduced diffusion resistance. As a result, the aerogel harvests a record hydrogen evolution rate (347\u00a0mmol\u00a0g<jats:sup>\u22121<\/jats:sup>\u00a0h<jats:sup>\u22121<\/jats:sup>) in an ultrahigh\u2010density formic acid of 19.8\u00a0g\u00a0L<jats:sup>\u22121<\/jats:sup>, around two times the rate promotion and ten times the density improvement compared to the state\u2010of\u2010the\u2010art materials and systems. The strategy presents an approach for the dehydrogenation of liquid hydrogen carriers, e.g., formic acid, formaldehyde, and hydrazine hydrate, concurrently ensuring high\u2010performance hydrogen release and high hydrogen storage density.<\/jats:p>","DOI":"10.1002\/smll.202204647","type":"journal-article","created":{"date-parts":[[2022,10,31]],"date-time":"2022-10-31T03:25:07Z","timestamp":1667186707000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Superaerophobic Resin\u2010Grafted rGO Aerogel with Boosted Product Removal Delivering High\u2010Performance Hydrogen Release at Ultrahigh Storage Density"],"prefix":"10.1002","volume":"18","author":[{"given":"Qian","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingsen","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"He","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Thermo\u2010fluid Science and Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dawei","family":"Tang","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3458-1045","authenticated-orcid":false,"given":"Lin","family":"Li","sequence":"additional","affiliation":[{"name":"School of Energy and Power Engineering Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,10,30]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202101053"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.201700161"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201000023"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001818"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00515K"},{"key":"e_1_2_8_6_1","first-page":"14","volume":"9","author":"Onishi N.","year":"2019","journal-title":"Adv. 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