{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T16:20:38Z","timestamp":1792599638556,"version":"4.5.0"},"reference-count":43,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2022,11,26]],"date-time":"2022-11-26T00:00:00Z","timestamp":1669420800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52071225"],"award-info":[{"award-number":["52071225"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51672181"],"award-info":[{"award-number":["51672181"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2023,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Micro\u2010sized silicon (\u00b5Si) anode features fewer interfacial side reactions and lower costs compared to nanosized silicon, and has higher commercial value when applied as a lithium\u2010ion battery (LIB) anode. However, the high localized stress generated during (de)lithiation causes electrode breakdown and performance deterioration of the \u00b5Si anode. In this work, hollow graphitic carbons with tailored dual sizes are employed as conductive additives for the \u00b5Si anode to overcome electrode failure. The dual\u2010size hollow graphitic carbons (HGC) additives consist of particles with micrometer size similar to the \u00b5Si particles; these additives are used for strain regulation. Additionally, nanometer\u2010size particles similar to commercial carbon black Spheron (SP) are used mainly for kinetics acceleration. In addition to building an efficient conductive network, the dual\u2010size hollow graphitic carbon conductive additive prevents the fracture of the electrode by reducing local stress and alleviating volume expansion. The \u00b5Si anode with dual\u2010size hollow graphitic carbons as conductive additives achieves an impressive capacity of 651.4\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 500\u00a0cycles at a high current density of 2\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . These findings suggest that dual\u2010size hollow graphitic carbons are expected to be superior conductive additives for micro\u2010sized alloy anodes similar to \u00b5Si.\n                  <\/jats:p>","DOI":"10.1002\/smll.202205284","type":"journal-article","created":{"date-parts":[[2022,11,26]],"date-time":"2022-11-26T09:42:26Z","timestamp":1669455746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Strain Regulating and Kinetics Accelerating of Micro\u2010Sized Silicon Anodes via Dual\u2010Size Hollow Graphitic Carbons Conductive Additives"],"prefix":"10.1002","volume":"19","author":[{"given":"Qitao","family":"Shi","sequence":"first","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanhao","family":"Cheng","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Wang","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhua","family":"Zhou","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huy Quang","family":"Ta","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"},{"name":"Institute for Complex Materials IFW Dresden  20 Helmholtz Strasse 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueyu","family":"Lian","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaudia","family":"Kurtyka","sequence":"additional","affiliation":[{"name":"Centre of Polymer and Carbon Materials Polish Academy of Sciences  M. Curie\u2010Sklodowskiej 34 Zabrze 41\u2013819 Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Barbara","family":"Trzebicka","sequence":"additional","affiliation":[{"name":"Centre of Polymer and Carbon Materials Polish Academy of Sciences  M. Curie\u2010Sklodowskiej 34 Zabrze 41\u2013819 Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas","family":"Gemming","sequence":"additional","affiliation":[{"name":"Institute for Complex Materials IFW Dresden  20 Helmholtz Strasse 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4448-1569","authenticated-orcid":false,"given":"Mark H.","family":"R\u00fcmmeli","sequence":"additional","affiliation":[{"name":"Soochow Institute for Energy and Materials InnovationS College of Energy Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University  Suzhou 215006 Suzhou 215006 China"},{"name":"Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Soochow University  Suzhou Jiangsu 215123 P. R. China"},{"name":"Institute for Complex Materials IFW Dresden  20 Helmholtz Strasse 01069 Dresden Germany"},{"name":"Centre of Polymer and Carbon Materials Polish Academy of Sciences  M. Curie\u2010Sklodowskiej 34 Zabrze 41\u2013819 Poland"},{"name":"Institute of Environmental Technology VSB\u2010Technical University of Ostrava  17. Listopadu 15 Ostrava 70833 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,11,26]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201800561"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/35104644"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2022.04.005"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202000218"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/eom2.12091"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2021.12.004"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.10.026"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.125480"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201904508"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202004577"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.07.014"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ente.202000056"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201502959"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwab028"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.07.025"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-09510-5"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.8b00703"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201800752"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2014.04.006"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2017.04.065"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0608-7"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0601-1"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.6b00218"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.02.012"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1802"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal4373"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2020.09.094"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA00254B"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11581-019-03391-w"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2010.10.005"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2018.03.009"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2019.04.025"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/am504932j"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1149\/06609.0017ecst"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2019.101182"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.153664"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001161"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.201600079"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2014.09.069"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.228339"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2008.12.015"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4518-9"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp5121965"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202205284","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202205284","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202205284","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,25]],"date-time":"2024-01-25T00:05:16Z","timestamp":1706141116000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202205284"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,26]]},"references-count":43,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2023,1]]}},"alternative-id":["10.1002\/smll.202205284"],"URL":"https:\/\/doi.org\/10.1002\/smll.202205284","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,26]]},"assertion":[{"value":"2022-08-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-11-26","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2205284"}}