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However, it remains a significant challenge to synthesize 2D Fe\u2010chalcogenides with specific phases in a controllable manner since Fe\u2010chalcogenides have multiple phases. Herein, a molecular sieve\u2010assisted strategy is reported for synthesizing ultrathin 2D iron sulfide on substrates via the chemical vapor deposition method. Using a molecular sieve and tuning growth temperatures to control the partial pressures of precursor concentrations, hexagonal FeS, tetragonal FeS, and non\u2010stoichiometric Fe<jats:sub>7<\/jats:sub>S<jats:sub>8<\/jats:sub> nanoflakes can be precisely synthesized. The 2D h\u2010FeS, t\u2010FeS, and Fe<jats:sub>7<\/jats:sub>S<jats:sub>8<\/jats:sub> have high conductivities of 5.4 \u00d7 10<jats:sup>5<\/jats:sup> S m<jats:sup>\u22121<\/jats:sup>, 5.8 \u00d7 10<jats:sup>5<\/jats:sup> S m<jats:sup>\u22121<\/jats:sup>, and 1.9 \u00d7 10<jats:sup>6<\/jats:sup> S m<jats:sup>\u22121<\/jats:sup>. 2D tetragonal FeS shows a superconducting transition at 4 K. The spin reorientation at \u224830 K on the non\u2010stoichiometric Fe<jats:sub>7<\/jats:sub>S<jats:sub>8<\/jats:sub> nanoflakes with ferrimagnetism up to room temperature has also been observed. The controllable synthesis of various phases of 2D iron sulfide may provide a route for synthesizing other 2D compounds with various phases.<\/jats:p>","DOI":"10.1002\/smll.202207325","type":"journal-article","created":{"date-parts":[[2023,3,15]],"date-time":"2023-03-15T08:30:44Z","timestamp":1678869044000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["The Controllable Synthesis of High\u2010Quality Two\u2010Dimensional Iron Sulfide with Specific Phases"],"prefix":"10.1002","volume":"19","author":[{"given":"Bicheng","family":"Wang","sequence":"first","affiliation":[{"name":"College of Chemistry Fuzhou University  Fuzhou 350108 P. R. 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