{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T08:37:57Z","timestamp":1790152677331,"version":"4.0.1"},"reference-count":60,"publisher":"Wiley","issue":"46","license":[{"start":{"date-parts":[[2023,7,28]],"date-time":"2023-07-28T00:00:00Z","timestamp":1690502400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2023,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>It is urgent to design a low\u2010cost electrocatalyst with high activity to enhance the efficiency of oxygen evolution reaction (OER), which is limited by the slow four\u2010electron transfer kinetics process. Nevertheless, traditional synthetic methods, including calcination and solvothermal, of the electrocatalysts are high\u2010cost, low\u2010yield, and energy\u2010hogging, which limits their industrial application. Herein, an ambient fast synthetic method is developed to prepare terrace\u2010like Fe\/Co bimetal\u2010organic framework (TFC\u2010MOF) electrocatalyst materials in gram scale in 1\u00a0h. The method in this paper is designable based on coordination chemistry. Fe and Co ions can coordinate with the carboxyl groups on benzene\u20101,3,5\u2010tricarboxylic acid (H<jats:sub>3<\/jats:sub>BTC) to form a 2D\u2010MOF structure. Structural characterizations, including SEM, TEM, and XRD are conducted to verify that the TFC\u2010MOF is a terrace\u2010like layered structure with uniform\u2010sized mesoporous, which reduces the adsorption steric hindrance and facilitates the mass and electron transfer efficiency of OER. The TFC\u2010MOF shows low overpotential, 255\u00a0mV at a current density of 10\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup>, and a low Tafel slope of 49.9\u00a0mV\u00a0dec<jats:sup>\u22121<\/jats:sup>, in an alkaline solution. This work provides a planar coordination strategy to synthesize 2D\u2010MOF OER electrocatalyst on a large scale with low cost and low energy consumption, which will promote its practical OER applications.<\/jats:p>","DOI":"10.1002\/smll.202207735","type":"journal-article","created":{"date-parts":[[2023,7,29]],"date-time":"2023-07-29T03:36:26Z","timestamp":1690601786000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Terrace\u2010Like 2D Hierarchically Porous Iron\/Cobalt Metal\u2013Organic Framework: Ambient Fast Synthesis and Efficient Oxygen Evolution Reaction Application"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0304-3228","authenticated-orcid":false,"given":"Tian","family":"Gao","sequence":"first","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8566-2198","authenticated-orcid":false,"given":"Yan","family":"Cai","sequence":"additional","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Wan","sequence":"additional","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peixuan","family":"Deng","sequence":"additional","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qun","family":"Cai","sequence":"additional","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Liu","sequence":"additional","affiliation":[{"name":"Hubei Province Key Laboratory for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Institute of Advanced Materials and Nanotechnology Wuhan University of Science and Technology  Wuhan 430081 P. R. China"},{"name":"School of Chemical and Environmental Engineering Wuhan Polytechnic University  Wuhan 430023 P. R. China"},{"name":"Hubei Key Laboratory of Radiation Chemistry and Functional Materials Hubei University of Science and Technology  Xianning 437100 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,7,28]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207044"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214264"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00328A"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA06529B"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c08147"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad4998"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav3506"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108133"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00766"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.04.012"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01942"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011347"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202200763"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202008787"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA03138K"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA07978H"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00311"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06962"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007496"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00268A"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910309"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09987"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA00413C"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201800584"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA09658C"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.12.013"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(19)63384-X"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901139"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00460"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms10942"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200304e"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja200559j"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.7b04646"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201604437"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA04331A"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201801065"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102632"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA06634K"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA05285E"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201704035"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA00410B"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120152"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4852"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aao0865"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1098\/rspa.1957.0108"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(73)90199-0"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2DT02303B"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2016.02.094"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.05.228"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202200270"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-019-03024-x"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-020-00528-9"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA07962H"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NA00112K"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2021.117290"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA07644B"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA03128B"},{"key":"e_1_2_7_58_1","doi-asserted-by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