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Herein, a boosting chemoselective hydrogenation strategy on Pt@Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>is proposed with gradient oxygen vacancy by synergy of hydrogen spillover and preferential adsorption. Experimental and theoretical investigations reveal that the nitro is preferentially adsorbed onto oxygen vacancy of Pt@Fe<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>, meanwhile, the H<jats:sub>2<\/jats:sub>dissociated on Pt nanoparticles and then spillover to approach the nitro for selective hydrogenation (&gt;99% conversion of 4\u2010nitrostyrene, &gt; 99% selectivity of 4\u2010aminostyrene, TOF of 2351\u00a0h<jats:sup>\u22121<\/jats:sup>). Moreover, the iron oxide support endows the catalyst magnetic retrievability. This high activity, selectivity, and easy recovery strategy provide a promising avenue for selective hydrogenation catalysis of various nitroaromatic.<\/jats:p>","DOI":"10.1002\/smll.202207918","type":"journal-article","created":{"date-parts":[[2023,1,21]],"date-time":"2023-01-21T03:30:51Z","timestamp":1674271851000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Boosting Chemoselective Hydrogenation of Nitroaromatic via Synergy of Hydrogen Spillover and Preferential Adsorption on Magnetically Recoverable Pt@Fe<sub>2<\/sub>O<sub>3<\/sub>"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4398-7410","authenticated-orcid":false,"given":"Guichu","family":"Yue","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioinspired Smart Interfacial Science and Technology of Ministry of Education School of Chemistry Beihang University Beijing 100191 P. R. 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