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Nevertheless, the deep\u2010rooted issues of dendrite formation and side reactions in unstable Zn metal anode have impeded RZIBs from being dependably deployed in their proposed applications. Herein, silk fibroin (SF) and lysozyme (ly), as natural biomacromolecules with abundant polar groups arranged in polypeptide backbones, are in situ self\u2010assembled on the Zn anode surface to construct a homogeneous and compact protein nanofilm. Such protein nanofilm protecting layer presents a negative charge surface and significantly regulates Zn<jats:sup>2+<\/jats:sup> deposition behavior. Meanwhile, synergistic flexible and robust features of protein nanofilm function as artificial solid electrolyte interface (SEI), accommodates the dynamic volume deformation during deposition\/dissolution, and blocks corrosion of side reactions. Consequently, the electrochemical stability of protein nanofilm\u2010modified Zn anode is greatly improved, with an excellent extended lifespan of over 1100\u00a0h at a high current density of 10\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup> and a high cycling capacity of 10\u00a0mAh\u00a0cm<jats:sup>\u22122<\/jats:sup>, corresponding to a high depth of discharge (83% DOD<jats:sub>Zn<\/jats:sub>). Furthermore, the highly reversible Zn electrode remarkably improved the overall performance of MnO<jats:sub>2<\/jats:sub>||Zn full\u2010cells.<\/jats:p>","DOI":"10.1002\/smll.202300895","type":"journal-article","created":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T12:45:06Z","timestamp":1682426706000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Self\u2010Assembled Protein Nanofilm Regulating Uniform Zn Nucleation and Deposition Enabling Long\u2010Life Zn Anodes"],"prefix":"10.1002","volume":"19","author":[{"given":"Bin","family":"Zhou","sequence":"first","affiliation":[{"name":"State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science, Fudan University  Shanghai 200433 P. R. 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