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However, due to the high flexibility, high steric hindrance, and low reactivity, it remains challenging to synthesize COFs using ketones as building units, especially the highly flexible aliphatic ones. Here, the single nickel site coordination strategy is reported to lock the configurations of the highly flexible diketimine to transform discrete oligomers or amorphous polymers into highly crystalline nickel\u2010diketimine\u2010linked COFs (named as Ni\u2010DKI\u2010COFs). The strategy has been successfully extended to the synthesis of a series of Ni\u2010DKI\u2010COFs by the condensation of three flexible diketones with two tridentate amines. 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