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However, the inevitable growth of dendrites will cause the rapid failure of battery especially under high current density. Herein, the utilization of tetrachloroethylene (C<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>) is reported as the electrolyte additive to induce the formation of the LiCl\u2010rich solid electrolyte interphase (SEI). Because of the lower Li ion diffusion barrier of LiCl, such SEI layer can supply sufficient pathway for rapid Li ion transport, alleviate the concentration polarization at the interface and inhibit the growth of Li dendrites. Meanwhile, the C<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub> can be continuously replenished during the cycle to ensure the stability of the SEI layer. With the aid of C<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>\u2010based electrolyte, the Li metal electrodes can maintain stable for &gt;300\u00a0h under high current density of 50\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup> with areal capacity of 5\u00a0mAh\u00a0cm<jats:sup>\u22122<\/jats:sup>, broadening the compatibility of lithium metal anode toward practical application scenarios.<\/jats:p>","DOI":"10.1002\/smll.202301433","type":"journal-article","created":{"date-parts":[[2023,6,2]],"date-time":"2023-06-02T07:42:23Z","timestamp":1685691743000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Achieving Stable Lithium Metal Anode at 50\u00a0mA\u00a0cm<sup>\u22122<\/sup> Current Density by LiCl Enriched SEI"],"prefix":"10.1002","volume":"19","author":[{"given":"Yuxin","family":"Fan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Electronic Thin Film and Integrated Devices University of 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