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In this study, a strain\u2010engineered Cs\n                    <jats:sub>3<\/jats:sub>\n                    Bi\n                    <jats:sub>2<\/jats:sub>\n                    Br\n                    <jats:sub>9<\/jats:sub>\n                    \/hierarchically porous BiVO\n                    <jats:sub>4<\/jats:sub>\n                    (s\u2010CBB\/HP\u2010BVO) heterojunction with improved charge separation and tailored CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption\/activation capability is developed. Density functional theory calculations suggest that the presence of tensile strain in Cs\n                    <jats:sub>3<\/jats:sub>\n                    Bi\n                    <jats:sub>2<\/jats:sub>\n                    Br\n                    <jats:sub>9<\/jats:sub>\n                    can significantly downshift the p\u2010band center of the active Bi atoms, which enhances the adsorption\/activation of inert CO\n                    <jats:sub>2<\/jats:sub>\n                    . Meanwhile, in situ irradiation X\u2010ray photoelectron spectroscopy and electron spin resonance confirm that efficient charge transfer occurs in s\u2010CBB\/HP\u2010BVO following an S\u2010scheme with built\u2010in electric field acceleration. Therefore, the well\u2010designed s\u2010CBB\/HP\u2010BVO heterojunction exhibits a boosted photocatalytic activity, with a total electron consumption rate of 70.63 \u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and 79.66% selectivity of CO production. Additionally, in situ diffuse reflectance infrared Fourier transform spectroscopy reveals that CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction undergoes a formaldehyde\u2010mediated reaction process. This work provides insight into strain engineering to improve the photocatalytic performance of halide perovskite.\n                  <\/jats:p>","DOI":"10.1002\/smll.202302058","type":"journal-article","created":{"date-parts":[[2023,5,14]],"date-time":"2023-05-14T23:45:40Z","timestamp":1684107940000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":53,"title":["Strain\u2010Engineering of Mesoporous Cs\n                    <sub>3<\/sub>\n                    Bi\n                    <sub>2<\/sub>\n                    Br\n                    <sub>9<\/sub>\n                    \/BiVO\n                    <sub>4<\/sub>\n                    S\u2010Scheme Heterojunction for Efficient CO\n                    <sub>2<\/sub>\n                    Photoreduction"],"prefix":"10.1002","volume":"19","author":[{"given":"Biao","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Environment and Energy, State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling South China University of Technology  Guangzhou 510000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Environment and Energy, State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling South China University of Technology  Guangzhou 510000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liqin","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Environment and Energy, State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Recycling South China University of Technology  Guangzhou 510000 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