{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T18:06:01Z","timestamp":1791223561603,"version":"4.1.0"},"reference-count":51,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2023,6,7]],"date-time":"2023-06-07T00:00:00Z","timestamp":1686096000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52073044"],"award-info":[{"award-number":["52073044"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U21A20330"],"award-info":[{"award-number":["U21A20330"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51873076"],"award-info":[{"award-number":["51873076"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52073118"],"award-info":[{"award-number":["52073118"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002838","name":"Changchun Institute of Applied Chemistry","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002838","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["2022\u201019"],"award-info":[{"award-number":["2022\u201019"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2023,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The low ionic conductivity and Li<jats:sup>+<\/jats:sup> transference number () of solid polymer electrolytes (SPEs) seriously hinder their application in lithium\u2010ion batteries (LIBs). In this study, a novel single\u2010ion lithium\u2010rich imidazole anionic porous aromatic framework (PAF\u2010220\u2010Li) is designed. The abundant pores in PAF\u2010220\u2010Li are conducive to the Li<jats:sup>+<\/jats:sup> transfer. Imidazole anion has\u00a0low binding force with Li<jats:sup>+<\/jats:sup>. The conjugation of imidazole and benzene ring can further reduce the binding energy between Li<jats:sup>+<\/jats:sup> and anions. Thus, only Li<jats:sup>+<\/jats:sup> moved freely in the SPEs, remarkably reducing the concentration polarization and inhibiting lithium dendrite growth. PAF\u2010220\u2010quasi\u2010solid polymer electrolyte (PAF\u2010220\u2010QSPE) is prepared through solution casting of Bis(trifluoromethane)sulfonimide lithium (LiTFSI) infused PAF\u2010220\u2010Li and Poly(vinylidene fluoride\u2010co\u2010hexafluoropropylene)(PVDF\u2010HFP), and possessed excellent electrochemical performance. The electrochemical property are further improved by preparing all\u2010solid polymer electrolyte (PAF\u2010220\u2010ASPE) via pressing\u2010disc method, which has a high Li<jats:sup>+<\/jats:sup> conductivity of 0.501\u00a0mS\u00a0cm<jats:sup>\u22121<\/jats:sup> and  of 0.93. The discharge specific capacity at 0.2\u00a0C of Li\/\/PAF\u2010220\u2010ASPE\/\/LFP reached 164\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup>, and the capacity retention rate is 90% after 180 cycles. This study provided a promising strategy for SPE with single\u2010ion PAFs to achieve high\u2010performance solid\u2010state LIBs.<\/jats:p>","DOI":"10.1002\/smll.202302818","type":"journal-article","created":{"date-parts":[[2023,6,7]],"date-time":"2023-06-07T17:46:34Z","timestamp":1686159994000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Single\u2010Ion Polymer Electrolyte Based on Lithium\u2010Rich Imidazole Anionic Porous Aromatic Framework for High Performance Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"19","author":[{"given":"Zhangnan","family":"Li","sequence":"first","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liying","family":"Wang","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhan","family":"Liu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengxuan","family":"Yu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baijun","family":"Liu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Jilin University  Changchun 130012 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongfeng","family":"Men","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyan","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5499-3437","authenticated-orcid":false,"given":"Wei","family":"Hu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangshan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Northeast Normal University  Changchun 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,6,7]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2014.6"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2007.411"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4821"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-018-0237-6"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000455"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007598"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201805301"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202101380"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202006381"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202103049"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.10.017"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201908701"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000831"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202209828"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.03.004"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.07.022"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003836"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02448"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201913380"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00543"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509014"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QM00936A"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007172"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c07418"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202206976"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.11.005"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202008208"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-4095(199804)10:6<439::AID-ADMA439>3.0.CO;2-I"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101537"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201901047"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201803422"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA05787C"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509014"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202102583"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12292"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05568"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2021.159890"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601625"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201604460"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201909267"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709774"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016716"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.06.030"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130527"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2018.07.007"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201410"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202009718"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202107444"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c15810"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202302818","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,12]],"date-time":"2023-10-12T06:51:23Z","timestamp":1697093483000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202302818"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,6,7]]},"references-count":51,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2023,10]]}},"alternative-id":["10.1002\/smll.202302818"],"URL":"https:\/\/doi.org\/10.1002\/smll.202302818","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,6,7]]},"assertion":[{"value":"2023-04-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-06-07","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2302818"}}