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Therefore, it is important to realize multicolor luminescence in a phosphor with single host and single activator as well as moisture resistance. LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup>@SiO<jats:sub>2<\/jats:sub> yolk\u2010shell nanospheres are facilely obtained by a designing new technology of a simple and cost\u2010effective electrospray ionization combined with a dicrucible fluorating technique without using protective gas. In addition, tunable photoluminescence, especially white\u2010light emission, is successfully obtained in LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup>@SiO<jats:sub>2<\/jats:sub> yolk\u2010shell nanospheres by adjusting Pr<jats:sup>3+<\/jats:sup> ion concentrations, and the luminescence mechanism of Pr<jats:sup>3+<\/jats:sup> ion is advanced. Compared with the counterpart LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup> nanospheres, the water stability of LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup>@SiO<jats:sub>2<\/jats:sub> yolk\u2010shell nanospheres is improved by 15% after immersion in water for 72\u00a0h, and the fluorescence intensity can be maintained at 86% of the initial intensity. Furthermore, by treating the yolk\u2010shell nanospheres with hydrofluoric acid, it is not only demonstrated that the shell\u2010layer is SiO<jats:sub>2<\/jats:sub> but also core\u2010LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup> nanospheres are obtained. Particularly, only fluorination procedure among the halogenation can produce such special yolk\u2010shell nanospheres, the formation mechanism of yolk\u2010shell nanospheres is proposed detailedly based on the sound experiments and a corresponding new technology is built. These findings broaden practical applications of LaF<jats:sub>3<\/jats:sub>:Pr<jats:sup>3+<\/jats:sup>@SiO<jats:sub>2<\/jats:sub> yolk\u2010shell nanospheres.<\/jats:p>","DOI":"10.1002\/smll.202305287","type":"journal-article","created":{"date-parts":[[2023,9,1]],"date-time":"2023-09-01T04:20:21Z","timestamp":1693542021000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Facilely Direct Construction, White\u2010Light Emission, and Color\u2010Adjustable Luminescence of LaF<sub>3<\/sub>:Pr<sup>3+<\/sup>@SiO<sub>2<\/sub> Yolk\u2010Shell Nanospheres with Moisture Resistance"],"prefix":"10.1002","volume":"20","author":[{"given":"Ning","family":"Li","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Changchun University of Science and Technology  Changchun 130022 China"},{"name":"Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province Changchun 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