{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T20:28:40Z","timestamp":1790713720779,"version":"4.1.0"},"reference-count":89,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2023,12,10]],"date-time":"2023-12-10T00:00:00Z","timestamp":1702166400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004480","name":"Natural Science Foundation of Shanxi Province","doi-asserted-by":"publisher","award":["202103021223457"],"award-info":[{"award-number":["202103021223457"]}],"id":[{"id":"10.13039\/501100004480","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2022M713254"],"award-info":[{"award-number":["2022M713254"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100019044","name":"State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["2021BWZ011"],"award-info":[{"award-number":["2021BWZ011"]}],"id":[{"id":"10.13039\/501100019044","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100014988","name":"Program for the Scientific Activities of Selected Returned Overseas Professionals in Shaanxi Province","doi-asserted-by":"publisher","award":["20220052"],"award-info":[{"award-number":["20220052"]}],"id":[{"id":"10.13039\/501100014988","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22202228"],"award-info":[{"award-number":["22202228"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22002067"],"award-info":[{"award-number":["22002067"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Incorporating metal clusters into the confined cavities of metal\u2212organic frameworks (MOFs) to form MOF\u2010supported catalysts has attracted considerable research interest with regard to carbonylation reactions. Herein, a self\u2010templating method is used to prepare the zinc oxide (ZnO)\u2010supported core\u2013shell catalyst ZnO@Pd\/ZIF\u20108. This facile strategy controls the growth of metal sources on the ZIF\u20108 shell layer and avoids the metal diffusion or aggregation problems of the conventional synthesis method. The characteristics of the catalysts show that the palladium (Pd) clusters are highly dispersed with an average particle size of \u22481.2\u00a0nm, making them excellent candidates as a catalyst for carbonylation under mild conditions. The optimal catalyst (1.25\u2010ZnO@Pd\/ZIF\u20108) exhibits excellent activity in synthesizing \u03b1, \u03b2\u2010alkynyl ketones under 1 atm of carbon monooxide (CO), and the conversion rate of 1, 3\u2010diphenylprop\u20102\u2010yn\u20101\u2010one is 3.09 and 3.87 times more than those of Pd\/ZIF\u20108 and Pd<jats:sup>2+<\/jats:sup>, respectively, for the first 2\u00a0h. Moreover, the 1.25\u2010ZnO@Pd\/ZIF\u20108 is recyclable, showing negligible metal leaching, and, under the conditions used in this investigation, can be reused at least five times without considerable loss in its catalytic efficiency. This protocol can also be applied with other nucleophile reagents to synthesize esters, amides, and acid products.<\/jats:p>","DOI":"10.1002\/smll.202306794","type":"journal-article","created":{"date-parts":[[2023,12,11]],"date-time":"2023-12-11T03:06:13Z","timestamp":1702263973000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Platform for the Immobilizing of Ultrasmall Pd Clusters for Carbonylation: In Situ Self\u2010Templating Fabrication of ZIF\u20108 on ZnO"],"prefix":"10.1002","volume":"20","author":[{"given":"Wei","family":"Yang","sequence":"first","affiliation":[{"name":"Institute of Coal Chemistry State Key Laboratory of Coal Conversion Chinese Academy of Sciences  Taiyuan Shanxi 030001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangchao","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Coal Chemistry State Key Laboratory of Coal Conversion Chinese Academy of Sciences  Taiyuan Shanxi 030001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"He","family":"Wang","sequence":"additional","affiliation":[{"name":"The third Military Representative Office in Taiyuan  Taiyuan Shanxi 030001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ding","family":"Ding","sequence":"additional","affiliation":[{"name":"Institute of Coal Chemistry State Key Laboratory of Coal Conversion Chinese Academy of Sciences  Taiyuan Shanxi 030001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaohua","family":"Jiang","sequence":"additional","affiliation":[{"name":"Jiangsu Co\u2010Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and Materials College of Materials Science and Engineering Nanjing Forestry University  Nanjing 210037 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9568-3702","authenticated-orcid":false,"given":"Guoying","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Coal Chemistry State Key Laboratory of Coal Conversion Chinese Academy of Sciences  Taiyuan Shanxi 030001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,10]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812842"},{"key":"e_1_2_9_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00803A"},{"key":"e_1_2_9_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202200128"},{"key":"e_1_2_9_1_4","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000304"},{"key":"e_1_2_9_1_5","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03789C"},{"key":"e_1_2_9_1_6","doi-asserted-by":"publisher","DOI":"10.1039\/D3QO01070H"},{"key":"e_1_2_9_1_7","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.3c00039"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115497"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC06056A"},{"key":"e_1_2_9_2_3","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00182G"},{"key":"e_1_2_9_2_4","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201600138"},{"key":"e_1_2_9_2_5","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02145"},{"key":"e_1_2_9_2_6","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801128"},{"key":"e_1_2_9_2_7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502405"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja306178q"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.02.078"},{"key":"e_1_2_9_3_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-34123-w"},{"key":"e_1_2_9_3_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507134"},{"key":"e_1_2_9_3_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202215529"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202017086"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900600"},{"key":"e_1_2_9_4_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.tibtech.2019.01.004"},{"key":"e_1_2_9_4_4","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07629"},{"key":"e_1_2_9_4_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702944"},{"key":"e_1_2_9_4_6","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c00950"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00196a"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2012.01.105"},{"key":"e_1_2_9_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902906"},{"key":"e_1_2_9_5_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.06.104"},{"key":"e_1_2_9_5_5","doi-asserted-by":"publisher","DOI":"10.1021\/jo050760y"},{"key":"e_1_2_9_5_6","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200801176"},{"key":"e_1_2_9_5_7","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2007.06.015"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC03697F"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.8b02886"},{"key":"e_1_2_9_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201001864"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201600744"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.4280"},{"key":"e_1_2_9_7_3","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC05280B"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.11.010"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01773A"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900013"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201311198"},{"key":"e_1_2_9_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000460"},{"key":"e_1_2_9_10_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214900"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201600570"},{"key":"e_1_2_9_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC07269K"},{"key":"e_1_2_9_11_3","doi-asserted-by":"publisher","DOI":"10.1039\/C6GC03027K"},{"key":"e_1_2_9_11_4","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC00740C"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.201700384"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0RA03406A"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cy00516f"},{"key":"e_1_2_9_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA18692G"},{"key":"e_1_2_9_13_3","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA04985D"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201402167"},{"key":"e_1_2_9_14_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-019-1204-y"},{"key":"e_1_2_9_14_3","doi-asserted-by":"publisher","DOI":"10.1039\/D1RA05177F"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA04910B"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC09918E"},{"key":"e_1_2_9_15_3","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ05089B"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2015.05.021"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c00552"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs400232b"},{"key":"e_1_2_9_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CY00488D"},{"key":"e_1_2_9_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201701439"},{"key":"e_1_2_9_17_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011068"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00223"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202107459"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.11.023"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08968"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00829A"},{"key":"e_1_2_9_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA09579C"},{"key":"e_1_2_9_22_3","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00094C"},{"key":"e_1_2_9_22_4","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00368F"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201501710"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1NJ03738B"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12261"},{"key":"e_1_2_9_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00769-4"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2014.06.009"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2014.10.023"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2022.119057"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2011.12.011"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2022.09.012"},{"key":"e_1_2_9_28_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122064"},{"key":"e_1_2_9_28_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40640-z"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja508588b"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b01392"},{"key":"e_1_2_9_29_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c02712"},{"key":"e_1_2_9_30_1","unstructured":"CCDC\u20102270437."},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201800177"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202306794","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,5,2]],"date-time":"2024-05-02T07:19:48Z","timestamp":1714634388000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202306794"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,12,10]]},"references-count":89,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2024,5]]}},"alternative-id":["10.1002\/smll.202306794"],"URL":"https:\/\/doi.org\/10.1002\/smll.202306794","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,12,10]]},"assertion":[{"value":"2023-08-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-12-10","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2306794"}}