{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T18:12:46Z","timestamp":1790273566810,"version":"4.1.0"},"reference-count":52,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2023,12,24]],"date-time":"2023-12-24T00:00:00Z","timestamp":1703376000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003787","name":"Natural Science Foundation of Hebei Province","doi-asserted-by":"publisher","award":["A2021208015"],"award-info":[{"award-number":["A2021208015"]}],"id":[{"id":"10.13039\/501100003787","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Vanadium\u2010based compounds are identified as promising cathode materials for aqueous zinc ion batteries due to their high specific capacity. However, the low intrinsic conductivity and sluggish Zn\n                    <jats:sup>2+<\/jats:sup>\n                    diffusion kinetics seriously impede their further practical application. Here, oxygen vacancies on\u00a0NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    is reported as a high\u2010performing cathode material for aqueous zinc ion batteries via a facile hydrothermal strategy. The introduction of oxygen vacancy accelerates the ion and charge transfer kinetics, reduces the diffusion barrier of zinc ions, and establishes a stable crystal structure during zinc ion (de\u2010intercalation). As a result, the oxygen vacancy enriched NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    exhibits a high specific capacity of \u2248499\u00a0mA\u00a0h\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , an excellent rate capability of 296\u00a0mA\u00a0h\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and the specific capacity cycling stability with 95.1% retention at 5\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for 4000 cycles, superior to the NVO sample (186.4\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 66% capacity retention).\n                  <\/jats:p>","DOI":"10.1002\/smll.202306972","type":"journal-article","created":{"date-parts":[[2023,12,24]],"date-time":"2023-12-24T23:34:28Z","timestamp":1703460868000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Oxygen Vacancies on NH\n                    <sub>4<\/sub>\n                    V\n                    <sub>4<\/sub>\n                    O\n                    <sub>10<\/sub>\n                    Accelerate Ion and Charge Transfer in Aqueous Zinc\u2013Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Yuqi","family":"Peng","sequence":"first","affiliation":[{"name":"Key Laboratory of Photovoltaic and Energy Conservation Materials CAS Institute of Solid State Physics Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 P. R. China"},{"name":"University of Science and Technology of China  96 Jinzhai Road, Baohe District Hefei Anhui 230026 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li'e","family":"Mo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photovoltaic and Energy Conservation Materials CAS Institute of Solid State Physics Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 P. R. China"},{"name":"University of Science and Technology of China  96 Jinzhai Road, Baohe District Hefei Anhui 230026 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Wei","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photovoltaic and Energy Conservation Materials CAS Institute of Solid State Physics Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 P. R. 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