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However, the high surface alkalinity and detrimental interfacial stability lead to the parasitic reaction and a series of phase deterioration. Herein, in situ cross\u2010linking binder molecular chains with a 3D network structure to construct a stable and robust electrode\u2013electrolyte interface, which can maintain the structural integrity and restrain side reactions is designed. Simultaneously, the cross\u2010linked polymer can form stable hydrogen bonds with the pristine binder, greatly enhancing the bonding property. More importantly, the functional groups contained in the cross\u2010linked co\u2010polymers can chemically anchor transition metals, effectively preventing the dissolution of transition metals. Theoretical calculations confirm the feasibility and advancement of the anchoring mechanism, driving excellent structural stability and inhibition of the NiO impurity phase. This work provides a practical strategy to realize the high stability of cathode materials.\n                  <\/jats:p>","DOI":"10.1002\/smll.202307227","type":"journal-article","created":{"date-parts":[[2023,11,8]],"date-time":"2023-11-08T15:44:58Z","timestamp":1699458298000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Chemical Cross\u2010linked Electrode\u2013Electrolyte Interface Boosting the Structural Integrity of High Nickel Cathode Materials"],"prefix":"10.1002","volume":"20","author":[{"given":"Yang","family":"Zhang","sequence":"first","affiliation":[{"name":"National Special Superfine Powder Engineering Research Center School of Chemistry and Chemical Engineering Nanjing University of Science and Technology  Nanjing 210094 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Soft Chemistry and Functional Materials of Education Ministry School of Chemistry and Chemical Engineering Nanjing University of Science and Technology  Nanjing 210094 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6912-0797","authenticated-orcid":false,"given":"Jie","family":"Liu","sequence":"additional","affiliation":[{"name":"National Special Superfine Powder Engineering Research Center School of Chemistry and Chemical Engineering Nanjing University of Science and Technology  Nanjing 210094 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_7_2_1","volume":"6","author":"Gao H.","year":"2016","journal-title":"Adv. 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