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Despite recent studies that have provided some guidelines in understanding and designing structural flexibility for controlling gate opening by chemical modification of the secondary building units, currently, there is no established strategy to design a flexible MOF showing selective gated adsorption for a specific guest molecule. In a present contribution it is demonstrated for the first time, that the selectivity in the gate opening of a particular compound can be tuned, changed, and even reversed using particle size engineering DUT\u20108(Zn) ([Zn\n                    <jats:sub>2<\/jats:sub>\n                    (2,6\u2010ndc)\n                    <jats:sub>2<\/jats:sub>\n                    (dabco)]\n                    <jats:sub>n<\/jats:sub>\n                    , 2,6\u2010ndc\u00a0=\u00a02,6\u2010naphthalenedicarboxylate, dabco\u00a0=\u00a01,4\u2010diazabicyclo\u2010[2.2.2]\u2010octane, DUT = Dresden University of Technology) experiences phase transition from open (\n                    <jats:italic>op<\/jats:italic>\n                    ) to closed (\n                    <jats:italic>cp<\/jats:italic>\n                    ) pore phase upon removal of solvent from the pores. Microcrystals show selective reopening in the presence of dichloromethane (DCM) over alcohols. Crystal downsizing to micron size unexpectedly reverses the gate opening selectivity, causing DUT\u20108(Zn) to open its nanosized pores for alcohols but suppressing the responsivity toward DCM.\n                  <\/jats:p>","DOI":"10.1002\/smll.202307285","type":"journal-article","created":{"date-parts":[[2024,1,15]],"date-time":"2024-01-15T23:48:06Z","timestamp":1705362486000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Chemoselectivity Inversion of Responsive Metal\u2013Organic Frameworks by Particle Size Tuning in the Micrometer Regime"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8754-4374","authenticated-orcid":false,"given":"Leila","family":"Abylgazina","sequence":"first","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7052-1029","authenticated-orcid":false,"given":"Irena","family":"Senkovska","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard","family":"Engemann","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nadine","family":"B\u00f6nisch","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0911-2039","authenticated-orcid":false,"given":"Tatiana E.","family":"Gorelik","sequence":"additional","affiliation":[{"name":"Electron Microscopy Group of Materials Science (EMMS), Central Facility for Electron Microscopy Universit\u00e4t Ulm  Oberberghof 3\/1 89081 Ulm Germany"},{"name":"Department Structure and Function of Proteins Helmholtz Centre for Infection Research  Inhoffenstra\u00dfe 7 38124 Braunschweig Germany"},{"name":"Helmholtz Institute for Pharmaceutical Research Saarland Helmholtz Centre for Infection Research Department of Pharmacy Saarland University  Universit\u00e4tscampus E8 1 66123 Saarbr\u00fccken Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3900-4442","authenticated-orcid":false,"given":"Christopher","family":"Bachetzky","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0582-4044","authenticated-orcid":false,"given":"Ute","family":"Kaiser","sequence":"additional","affiliation":[{"name":"Electron Microscopy Group of Materials Science (EMMS), Central Facility for Electron Microscopy Universit\u00e4t Ulm  Oberberghof 3\/1 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3511-9899","authenticated-orcid":false,"given":"Eike","family":"Brunner","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4572-0303","authenticated-orcid":false,"given":"Stefan","family":"Kaskel","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Dresden  Bergstr. 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004535"},{"key":"e_1_2_8_1_2","volume":"62","author":"Senkovska I.","journal-title":"Angew. 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