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Herein, the ultrathin NiV\u2010LDH (u\u2010NiV\u2010LDH) with abundant defects is successfully synthesized, and the defect\u2010enriched structure is finely determined by X\u2010ray adsorption fine structure etc. When applied for MOR, the as\u2010prepared u\u2010NiV\u2010LDH presents a low potential of 1.41\u00a0V versus RHE at 100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , which is much lower than that of bulk NiV\u2010LDH (1.75\u00a0V vs RHE) at the same current density. The yield of H\n                    <jats:sub>2<\/jats:sub>\n                    and formate is 98.2% and 88.1% as its initial over five cycles and the ultrathin structure of u\u2010NiV\u2010LDH can be well maintained. Various\n                    <jats:italic>operando<\/jats:italic>\n                    experiments and theoretical calculations prove that the few\u2010layer stacking structure makes u\u2010NiV\u2010LDH free from the interlayer hydrogen diffusion process and the hydrogen can be directly detached from LDH laminate. Moreover, the abundant surface defects upshift the d\u2010band center of u\u2010NiV\u2010LDH and endow a higher local methanol concentration, resulting in an accelerated dehydrogenation kinetics on u\u2010NiV\u2010LDH. The synergy of the proton detachment from the laminate and the methanol dehydrogenation oxidation contributes to the excellent MOR performance of u\u2010NiV\u2010LDH.\n                  <\/jats:p>","DOI":"10.1002\/smll.202307975","type":"journal-article","created":{"date-parts":[[2023,12,15]],"date-time":"2023-12-15T04:21:10Z","timestamp":1702614070000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Ultrathin NiV Layered Double Hydroxide for Methanol Electrooxidation: Understanding the Proton Detachment Kinetics and Methanol Dehydrogenation Oxidation"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4398-8771","authenticated-orcid":false,"given":"Zhaohui","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sha","family":"Bai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianyang","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guihao","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziheng","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihang","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoliang","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lirong","family":"Zheng","sequence":"additional","affiliation":[{"name":"Beijing Synchrotron Radiation Facility Institute of High Energy Physics Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1309-0626","authenticated-orcid":false,"given":"Yu\u2010Fei","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 P. R. China"},{"name":"Quzhou Institute for Innovation in Resource Chemical Engineering  Quzhou Zhejiang 324000 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,12,15]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300879"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00715-w"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00721-y"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2023.02.012"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-5329-8"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2022.03.042"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101522"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37441-9"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12192"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601657"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2020.118618"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2020.07.022"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31484-0"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02570"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40242-021-1358-1"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105320"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904246"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120669"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA09412B"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202209698"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202203787"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207236"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02628"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32443-5"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.12.013"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309478"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP01052A"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b04106"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29875-4"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30670-4"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202208027"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4858-5"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202317"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202107390"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202204089"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007056"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300935"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304646"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202307975","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,5,9]],"date-time":"2024-05-09T09:35:53Z","timestamp":1715247353000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202307975"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,12,15]]},"references-count":38,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2024,5]]}},"alternative-id":["10.1002\/smll.202307975"],"URL":"https:\/\/doi.org\/10.1002\/smll.202307975","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,12,15]]},"assertion":[{"value":"2023-09-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-12-15","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2307975"}}