{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T15:34:35Z","timestamp":1788881675520,"version":"build-2803163510"},"reference-count":56,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2023,12,27]],"date-time":"2023-12-27T00:00:00Z","timestamp":1703635200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22005250"],"award-info":[{"award-number":["22005250"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>By increasing the content of Ni<jats:sup>3+<\/jats:sup>, the catalytic activity of nickel\u2010based catalysts for the oxygen evolution reaction (OER), which is still problematic with current synthesis routes, can be increased. Herein, a Ni<jats:sup>3+<\/jats:sup>\u2010rich of Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS on FeNi Foam (Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS@FNF) via anodic electrodeposition to direct obtain high valence metal ions for OER catalyst is presented. XPS showed that the introduction of Fe not only further increased the Ni<jats:sup>3+<\/jats:sup> concentration in Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS to 95.02%, but also inhibited the dissolution of NiOOH by up to seven times. Furthermore, the OER kinetics is enhanced by the combination of the inner Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS heterostructures and the electrochemically induced surface layers of oxides\/hydroxides. Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS@FNF shows the most excellent OER activity with a low Tafel slope of 11.2\u00a0mV\u00a0dec<jats:sup>\u22121<\/jats:sup> and overpotentials of 196 and 445\u00a0mV at current densities of 10 and 1400\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup>, respectively. Furthermore, the Ni<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>\/FeS@FNF catalyst can be operated stably at 1500\u00a0mA\u00a0cm<jats:sup>\u22122<\/jats:sup> for 200\u00a0h without significant performance degradation. In conclusion, this work has significantly increased the high activity Ni<jats:sup>3+<\/jats:sup> content in nickel\u2010based OER electrocatalysts through an anodic electrodeposition strategy. The preparation process is time\u2010saving and mature, which is expected to be applied in large\u2010scale industrialization.<\/jats:p>","DOI":"10.1002\/smll.202308371","type":"journal-article","created":{"date-parts":[[2023,12,27]],"date-time":"2023-12-27T20:51:26Z","timestamp":1703710286000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["In Situ Fast Construction of Ni<sub>3<\/sub>S<sub>4<\/sub>\/FeS Catalysts on 3D Foam Structure Achieving Stable Large\u2010Current\u2010Density Water Oxidation"],"prefix":"10.1002","volume":"20","author":[{"given":"Pingping","family":"Tan","sequence":"first","affiliation":[{"name":"School of Materials and Energy Southwest University  Chongqing 400715 P. R. China"},{"name":"ZJU\u2010Hangzhou Global Scientific and Technological Innovation Centre Zhejiang University  Hangzhou 311200 P. R. 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