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However, its electrochemical kinetics are still hindered by the absence of sufficient and homogenous conductive wiring inside active microparticles. Herein, an in situ pillaring strategy of electronic nano\u2010wires is proposed to slice T\u2010Nb\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    laminated particles for the development of durable and fast\u2010charging anodes for Li\u2010ion batteries. A micro\u2010level layered structure consisting of nano\u2010carbon\u2010inserted T\u2010Nb\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    composite flakes is designed and enabled by successive ion exchange, slice exfoliation, in situ polymerization, and carbonization processes. The pillared carbon interlayer (derived from polyaniline) can serve as in\u2010built conductive wires to promote and homogenize electron transfer inside the micro\u2010level particles. The porous structure (formed by the self\u2010assembly of exfoliated flakes) contributes to the improved electrolyte immersion and enhanced lithium migration. Benefitting from the kinetically favorable effects, the modified T\u2010Nb\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    anode achieves the high\u2010rate capability (108.4 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10 A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and ultralong cycling durability (138 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1.0 A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 8000 cycles, with an average capacity decaying rate as small as 0.043\u2030). This work provides an effective strategy of electron wire pillaring with the slicing effect for laminated electrode materials with high tap density.\n                  <\/jats:p>","DOI":"10.1002\/smll.202308727","type":"journal-article","created":{"date-parts":[[2024,1,16]],"date-time":"2024-01-16T23:25:46Z","timestamp":1705447546000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Pillaring Electronic Nano\u2010Wires to Slice T\u2010Nb\n                    <sub>2<\/sub>\n                    O\n                    <sub>5<\/sub>\n                    Laminated Particles for Durable Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Yongjian","family":"Zheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  585 He Shuo Road Shanghai 201899 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 China"},{"name":"CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 201899 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keyi","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  585 He Shuo Road Shanghai 201899 China"},{"name":"CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 201899 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering School of Environmental and Chemical Engineering Shanghai University  Shangda Road 99 Shanghai 200444 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuangqiang","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering School of Environmental and Chemical Engineering Shanghai University  Shangda Road 99 Shanghai 200444 China"},{"name":"Institute for Carbon Neutralization College of Chemistry and Materials Engineering Wenzhou University  Wenzhou 325035 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5587-8617","authenticated-orcid":false,"given":"Chilin","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  585 He Shuo Road Shanghai 201899 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 China"},{"name":"CAS Key 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