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This work has synthesized an organic compound, triphenazino[2,3\u2010b](1,4,5,8,9,12\u2010hexaazatriphenylene) (TPHATP), with as high as 87.16% yield. This compound has a highly \u03c0\u2010conjugated and rigid molecular structure, which is synthesized by capping hexaketocyclohexane with three molecules of 2,3\u2010diaminophenazine derived from low\u2010cost o\u2010phenylenediamine, and is used as a cathode material for assembling aqueous rechargeable zinc ion batteries. Both experiments and DFT calculations demonstrate that the redox mechanism of TPHATP is predominantly governed by H<jats:sup>+<\/jats:sup> storage. The Zn\u2010intercalation product of nitride\u2010type compound, is too unstable to form in water. Moreover, the TPHATP cathode exhibits a capacity of as high as 318.3 mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at 0.1 A\u00a0g<jats:sup>\u22121<\/jats:sup>, and maintained a stable capacity of 111.9 mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at a large current density of 10 A\u00a0g<jats:sup>\u22121<\/jats:sup> for 5000 cycles with only a decay of 0.000512% per cycle. This study provides new insights into understanding pyrazine as an active redox group and offers a potential affordable aqueous battery system for grid\u2010scale energy storage.<\/jats:p>","DOI":"10.1002\/smll.202309022","type":"journal-article","created":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T21:54:57Z","timestamp":1702418097000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Engineering Low\u2010Cost Organic Cathode for Aqueous Rechargeable Battery and Demonstrating the Proton Intercalation Mechanism for Pyrazine Energy Storage Unit"],"prefix":"10.1002","volume":"20","author":[{"given":"Suyan","family":"Niu","sequence":"first","affiliation":[{"name":"Department of Chemistry Northeastern University  Shenyang 110819 P. R. 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