{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T02:53:28Z","timestamp":1788317608084,"version":"build-2803163510"},"reference-count":45,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2024,1,29]],"date-time":"2024-01-29T00:00:00Z","timestamp":1706486400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,1,29]],"date-time":"2024-01-29T00:00:00Z","timestamp":1706486400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100019923","name":"DEVCOM Army Research Laboratory","doi-asserted-by":"publisher","award":["W911NF\u201020\u20102\u20100284"],"award-info":[{"award-number":["W911NF\u201020\u20102\u20100284"]}],"id":[{"id":"10.13039\/100019923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Silicon anode is an appealing alternative to enhance the energy density of lithium\u2010ion batteries due to its high capacity, but it suffers from severe capacity fade caused by its fast degradation. The crossover of dissolved transition\u2010metal (TM) ions from the cathode to the anode is known to catalyze the decomposition of electrolyte on the graphite anode surface, but the relative impact of dissolved Mn\n                    <jats:sup>2+<\/jats:sup>\n                    versus Ni\n                    <jats:sup>2+<\/jats:sup>\n                    versus Co\n                    <jats:sup>2+<\/jats:sup>\n                    on silicon anode remains to be delineated. Since all three TM ions can dissolve from LiNi\n                    <jats:sub>1\u2212x\u2212y<\/jats:sub>\n                    Mn\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NMC) cathodes and migrate to the anode, here a LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    cathode is paired with SiO\n                    <jats:sub>x<\/jats:sub>\n                    anode and assess the impact by introducing a specific amount of Mn\n                    <jats:sup>2+<\/jats:sup>\n                    or Ni\n                    <jats:sup>2+<\/jats:sup>\n                    or Co\n                    <jats:sup>2+<\/jats:sup>\n                    ions into the electrolyte. It is found that Mn\n                    <jats:sup>2+<\/jats:sup>\n                    ions cause a much larger increase in SiO\n                    <jats:sub>x<\/jats:sub>\n                    electrode thickness during cycling due to increased electrolyte decomposition and solid\u2013electrolyte interphase (SEI) formation compared to Ni\n                    <jats:sup>2+<\/jats:sup>\n                    and Co\n                    <jats:sup>2+<\/jats:sup>\n                    ions, similar to previous findings with graphite anode. However, with a lower impedance, the SEI formed with Mn\n                    <jats:sup>2+<\/jats:sup>\n                    protects the Si anode from excessive degradation compared to that with Co\n                    <jats:sup>2+<\/jats:sup>\n                    or Ni\n                    <jats:sup>2+<\/jats:sup>\n                    ions. Thus, Mn\n                    <jats:sup>2+<\/jats:sup>\n                    ions have a less detrimental effect on Si anodes than Co\n                    <jats:sup>2+<\/jats:sup>\n                    or Ni\n                    <jats:sup>2+<\/jats:sup>\n                    ions, which is the opposite of that seen with graphite anodes.\n                  <\/jats:p>","DOI":"10.1002\/smll.202309350","type":"journal-article","created":{"date-parts":[[2024,1,29]],"date-time":"2024-01-29T05:41:18Z","timestamp":1706506878000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Delineating the Effects of Transition\u2010Metal\u2010Ion Dissolution on Silicon Anodes in Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Rudy Martin","family":"Torres","sequence":"first","affiliation":[{"name":"Materials Science &amp; Engineering Program and Texas Materials Institute The University of Texas at Austin  Austin TX 78721 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0237-9563","authenticated-orcid":false,"given":"Arumugam","family":"Manthiram","sequence":"additional","affiliation":[{"name":"Materials Science &amp; Engineering Program and Texas Materials Institute The University of Texas at Austin  Austin TX 78721 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,29]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02584"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA00361J"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA03108D"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8086278"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.11.013"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.04.013"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17686-4"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tsf.2018.03.037"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta11714f"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2006.09.084"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR05748J"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.09.009"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2007.411"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2017.07.073"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00441B"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2021.712225"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.9b01094"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2023.142105"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.358759"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00918-2"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05627-8"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.229246"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202100107"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c07932"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b11746"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0821915jes"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003738"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7EE03122J"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0013-4686(01)00847-7"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2012.01.122"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2014.04.091"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2016.08.099"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0511814jes"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17396-x"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202103611"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0161506jes"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1115\/1.4047222"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2020.101268"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1806878115"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201900209"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2016.04.008"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA05098C"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/0169-4332(93)90431-A"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfrep.2013.03.001"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-26894-5"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202309350","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202309350","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202309350","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T08:42:50Z","timestamp":1772959370000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202309350"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1,29]]},"references-count":45,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2024,7]]}},"alternative-id":["10.1002\/smll.202309350"],"URL":"https:\/\/doi.org\/10.1002\/smll.202309350","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,1,29]]},"assertion":[{"value":"2023-10-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-01-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2309350"}}