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By adding low concentration H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    under visible light irradiation, the Z\u2010scheme heterojunction and photocatalytic\u2010Fenton\u2010like reaction synergistically enhance the degradation and mineralization of ciprofloxacin (CIP). Among them, M50B150 showed efficient photodegradation efficiency and excellent cycling stability, with 94.6% removal of CIP (10\u00a0mg\u00a0L\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) by M50B150 (0.2\u00a0g\u00a0L\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) under 90\u00a0min of visible light. In the M\n                    <jats:italic>x<\/jats:italic>\n                    B\n                    <jats:italic>y<\/jats:italic>\n                    heterojunctions, the rapid transfer of photo\u2010generated electrons not only directly decomposed H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    to generate\n                    <jats:bold>\u00b7<\/jats:bold>\n                    OH, but also improved the cycle of Fe\n                    <jats:sup>3+<\/jats:sup>\n                    \/Fe\n                    <jats:sup>2+<\/jats:sup>\n                    pairs, which facilitated the reaction with H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    to generate\n                    <jats:bold>\u00b7<\/jats:bold>\n                    OH and\n                    <jats:bold>\u00b7<\/jats:bold>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    radicals. In addition, the effects of photocatalyst dosages, pH of CIP solution, and coexisting substances on CIP removal are systematically investigated. It is found that the photocatalytic\u2010 Fenton\u2010like reaction can be carried out at a pH close to neutral conditions. Finally, the charge transfer mechanism of the Z\u2010scheme is verified by electron spin resonance (ESR) signals. The ecotoxicity of CIP degradation products is estimated by the T.E.S.T tool, indicating that the constructed photocatalysis\u2010Fenton\u2010like system is a green wastewater treatment technology.\n                  <\/jats:p>","DOI":"10.1002\/smll.202309541","type":"journal-article","created":{"date-parts":[[2024,1,27]],"date-time":"2024-01-27T02:32:15Z","timestamp":1706322735000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":48,"title":["The Z\u2010Scheme MIL\u201088B(Fe)\/BiOBr Heterojunction Promotes Fe(III)\/Fe(II) Cycling and Photocatalytic\u2010Fenton\u2010Like Synergistically Enhances the Degradation of Ciprofloxacin"],"prefix":"10.1002","volume":"20","author":[{"given":"Tingting","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaiyue","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yansheng","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanhong","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongmei","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2719-5587","authenticated-orcid":false,"given":"Zhihua","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2027-5178","authenticated-orcid":false,"given":"Fubo","family":"Gu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing 100029 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,26]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.09.009"},{"key":"e_1_2_8_2_1","volume":"253","author":"Hu K.","year":"2020","journal-title":"J. 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