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However, limited by crystal disintegration and interfacial instability, bulk and interfacial failure plague their electrochemical performance. To address these challenges, a structural enhancement combined with surface modification is achieved through trace Y doping. Based on a synergistic combination of experimental results and density functional theory (DFT) calculations, the introduction of partial Y ions at the Na site (2d) acts as a stabilizing pillar, mitigating the electrostatic repulsions between adjacent TMO\n                    <jats:sub>2<\/jats:sub>\n                    slabs and thereby relieving internal structural stress. Furthermore, the presence of Y effectively optimizes the Ni 3d\u2010O 2p hybridization, resulting in enhanced electronic conductivity and a notable rapid charging ability, with a capacity of 77.3\u00a0mA h g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 40\u00a0C. Concurrently, the introduction of Y also induces the formation of perovskite nano\u2010islands, which serve to minimize side reactions and modulate interfacial diffusion. As a result, the refined P2\u2010Na\n                    <jats:sub>0.65<\/jats:sub>\n                    Y\n                    <jats:sub>0.025<\/jats:sub>\n                    [Ni\n                    <jats:sub>0.33<\/jats:sub>\n                    Mn\n                    <jats:sub>0.67<\/jats:sub>\n                    ]O\n                    <jats:sub>2<\/jats:sub>\n                    cathode material exhibits an exceptionally low volume variation (\u22481.99%), an impressive capacity retention of 83.3% even at \u221240\u00a0\u00b0C after1500 cycles at 1\u00a0C.\n                  <\/jats:p>","DOI":"10.1002\/smll.202310756","type":"journal-article","created":{"date-parts":[[2024,2,15]],"date-time":"2024-02-15T23:40:30Z","timestamp":1708040430000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Trace Y Doping Regulated Bulk\/Interfacial Reactions of P2\u2010Layered Oxides for Ultrahigh\u2010Rate Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Yong","family":"Li","sequence":"first","affiliation":[{"name":"Institute for Sustainable Energy\/College of Science Shanghai University  Shanghai 200444 P. 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